Bis{3-[2-(methyl­sulfon­yl)pyrimidin-4-yl]pyridinium} tetra­chloridocadmium

In the title compound, (C(10)H(10)N(3)O(2)S)(2)[CdCl(4)], the Cd(II) ion lies on a twofold axis and is coordinated by four chloride anions, with bond distances of 2.4787 (10) and 2.4410 (10) Å. A chain along the c axis is formed by C—H⋯N hydrogen-bonding inter­actions and a weak π–π inter­action is...

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Detalles Bibliográficos
Autores principales: Hu, Dahua, Liu, Xia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238717/
https://www.ncbi.nlm.nih.gov/pubmed/22199594
http://dx.doi.org/10.1107/S1600536811045995
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author Hu, Dahua
Liu, Xia
author_facet Hu, Dahua
Liu, Xia
author_sort Hu, Dahua
collection PubMed
description In the title compound, (C(10)H(10)N(3)O(2)S)(2)[CdCl(4)], the Cd(II) ion lies on a twofold axis and is coordinated by four chloride anions, with bond distances of 2.4787 (10) and 2.4410 (10) Å. A chain along the c axis is formed by C—H⋯N hydrogen-bonding inter­actions and a weak π–π inter­action is observed between the pyrimidine rings of two adjacent parallel chains [centroid–centroid distance = 3.722 (2) Å]. N—H⋯Cl, CN—H⋯Cl and N—H⋯O interactions also occur.
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spelling pubmed-32387172011-12-23 Bis{3-[2-(methyl­sulfon­yl)pyrimidin-4-yl]pyridinium} tetra­chloridocadmium Hu, Dahua Liu, Xia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(10)H(10)N(3)O(2)S)(2)[CdCl(4)], the Cd(II) ion lies on a twofold axis and is coordinated by four chloride anions, with bond distances of 2.4787 (10) and 2.4410 (10) Å. A chain along the c axis is formed by C—H⋯N hydrogen-bonding inter­actions and a weak π–π inter­action is observed between the pyrimidine rings of two adjacent parallel chains [centroid–centroid distance = 3.722 (2) Å]. N—H⋯Cl, CN—H⋯Cl and N—H⋯O interactions also occur. International Union of Crystallography 2011-11-23 /pmc/articles/PMC3238717/ /pubmed/22199594 http://dx.doi.org/10.1107/S1600536811045995 Text en © Hu and Liu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hu, Dahua
Liu, Xia
Bis{3-[2-(methyl­sulfon­yl)pyrimidin-4-yl]pyridinium} tetra­chloridocadmium
title Bis{3-[2-(methyl­sulfon­yl)pyrimidin-4-yl]pyridinium} tetra­chloridocadmium
title_full Bis{3-[2-(methyl­sulfon­yl)pyrimidin-4-yl]pyridinium} tetra­chloridocadmium
title_fullStr Bis{3-[2-(methyl­sulfon­yl)pyrimidin-4-yl]pyridinium} tetra­chloridocadmium
title_full_unstemmed Bis{3-[2-(methyl­sulfon­yl)pyrimidin-4-yl]pyridinium} tetra­chloridocadmium
title_short Bis{3-[2-(methyl­sulfon­yl)pyrimidin-4-yl]pyridinium} tetra­chloridocadmium
title_sort bis{3-[2-(methyl­sulfon­yl)pyrimidin-4-yl]pyridinium} tetra­chloridocadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238717/
https://www.ncbi.nlm.nih.gov/pubmed/22199594
http://dx.doi.org/10.1107/S1600536811045995
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AT liuxia bis32methylsulfonylpyrimidin4ylpyridiniumtetrachloridocadmium

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