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Tris(1,10-phenanthroline-κ(2) N,N′)nickel(II) bis(2,4,5-tricarboxybenzoate) monohydrate
In the title compound, [Ni(C(12)H(8)N(2))(3)](C(10)H(5)O(8))(2)·H(2)O, the Ni(II) cation is coordinated by six N atoms of the three bidentate chelating 1,10-phenanthroline ligands in a slightly distorted octahedral coordination geometry. The Ni—N bond lengths range from 2.074 (2) to 2.094 (2) Å. Th...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238718/ https://www.ncbi.nlm.nih.gov/pubmed/22199595 http://dx.doi.org/10.1107/S1600536811048914 |
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author | Zhong, Kai-Long Ni, Chao Qian, Ming-Yi |
author_facet | Zhong, Kai-Long Ni, Chao Qian, Ming-Yi |
author_sort | Zhong, Kai-Long |
collection | PubMed |
description | In the title compound, [Ni(C(12)H(8)N(2))(3)](C(10)H(5)O(8))(2)·H(2)O, the Ni(II) cation is coordinated by six N atoms of the three bidentate chelating 1,10-phenanthroline ligands in a slightly distorted octahedral coordination geometry. The Ni—N bond lengths range from 2.074 (2) to 2.094 (2) Å. The dihedral angles between the three chelating NCCN groups to each other are 85.71 (3), 73.75 (2) and 85.71 (3)°, respectively. The Ni cation, the phenyl ring of the 1,10-phenanthroline ligand and the lattice water molecule are located on special positions (site symmetry 2). In the crystal, the uncoordinated 2,4,5-tricarboxybenzenoate anions join with each other through O—H⋯O hydrogen bonds, forming a two-dimensional hydrogen-bonded layer structure along the bc plane. The layers are further linked via additional O—H⋯O interactions between water and carboxyl groups, resulting in a three-dimensional supramolecular network. |
format | Online Article Text |
id | pubmed-3238718 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32387182011-12-23 Tris(1,10-phenanthroline-κ(2) N,N′)nickel(II) bis(2,4,5-tricarboxybenzoate) monohydrate Zhong, Kai-Long Ni, Chao Qian, Ming-Yi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(12)H(8)N(2))(3)](C(10)H(5)O(8))(2)·H(2)O, the Ni(II) cation is coordinated by six N atoms of the three bidentate chelating 1,10-phenanthroline ligands in a slightly distorted octahedral coordination geometry. The Ni—N bond lengths range from 2.074 (2) to 2.094 (2) Å. The dihedral angles between the three chelating NCCN groups to each other are 85.71 (3), 73.75 (2) and 85.71 (3)°, respectively. The Ni cation, the phenyl ring of the 1,10-phenanthroline ligand and the lattice water molecule are located on special positions (site symmetry 2). In the crystal, the uncoordinated 2,4,5-tricarboxybenzenoate anions join with each other through O—H⋯O hydrogen bonds, forming a two-dimensional hydrogen-bonded layer structure along the bc plane. The layers are further linked via additional O—H⋯O interactions between water and carboxyl groups, resulting in a three-dimensional supramolecular network. International Union of Crystallography 2011-11-23 /pmc/articles/PMC3238718/ /pubmed/22199595 http://dx.doi.org/10.1107/S1600536811048914 Text en © Zhong et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhong, Kai-Long Ni, Chao Qian, Ming-Yi Tris(1,10-phenanthroline-κ(2) N,N′)nickel(II) bis(2,4,5-tricarboxybenzoate) monohydrate |
title | Tris(1,10-phenanthroline-κ(2)
N,N′)nickel(II) bis(2,4,5-tricarboxybenzoate) monohydrate |
title_full | Tris(1,10-phenanthroline-κ(2)
N,N′)nickel(II) bis(2,4,5-tricarboxybenzoate) monohydrate |
title_fullStr | Tris(1,10-phenanthroline-κ(2)
N,N′)nickel(II) bis(2,4,5-tricarboxybenzoate) monohydrate |
title_full_unstemmed | Tris(1,10-phenanthroline-κ(2)
N,N′)nickel(II) bis(2,4,5-tricarboxybenzoate) monohydrate |
title_short | Tris(1,10-phenanthroline-κ(2)
N,N′)nickel(II) bis(2,4,5-tricarboxybenzoate) monohydrate |
title_sort | tris(1,10-phenanthroline-κ(2)
n,n′)nickel(ii) bis(2,4,5-tricarboxybenzoate) monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238718/ https://www.ncbi.nlm.nih.gov/pubmed/22199595 http://dx.doi.org/10.1107/S1600536811048914 |
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