[μ-Bis(diphenyl­phosphan­yl-κP)methane]­deca­carbonyl­tri-μ-hydrido-trirhenium(I)(3 Re—Re) dichloromethane solvate

In the title compound, [Re(3)(μ-H)(3)(C(25)H(22)P(2))(CO)(10)]·CH(2)Cl(2), the three Re atoms form a triangle bearing ten terminal carbonyl groups and three edge-bridging hydrides. The bis­(diphenyl­phosphan­yl)methane ligand bridges two Re atoms. Neglecting the Re—Re inter­actions, each Re atom is...

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Autores principales: Abdel-Magied, Ahmed F., Singh, Amrendra K., Haukka, Matti, Nordlander, Ebbe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238719/
https://www.ncbi.nlm.nih.gov/pubmed/22199596
http://dx.doi.org/10.1107/S1600536811049312
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author Abdel-Magied, Ahmed F.
Singh, Amrendra K.
Haukka, Matti
Nordlander, Ebbe
author_facet Abdel-Magied, Ahmed F.
Singh, Amrendra K.
Haukka, Matti
Nordlander, Ebbe
author_sort Abdel-Magied, Ahmed F.
collection PubMed
description In the title compound, [Re(3)(μ-H)(3)(C(25)H(22)P(2))(CO)(10)]·CH(2)Cl(2), the three Re atoms form a triangle bearing ten terminal carbonyl groups and three edge-bridging hydrides. The bis­(diphenyl­phosphan­yl)methane ligand bridges two Re atoms. Neglecting the Re—Re inter­actions, each Re atom is in a slightly distorted octa­hedral coordination environment. The dichloro­methane solvent mol­ecule is disordered over two sets of sites with fixed occupancies of 0.6 and 0.4.
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spelling pubmed-32387192011-12-23 [μ-Bis(diphenyl­phosphan­yl-κP)methane]­deca­carbonyl­tri-μ-hydrido-trirhenium(I)(3 Re—Re) dichloromethane solvate Abdel-Magied, Ahmed F. Singh, Amrendra K. Haukka, Matti Nordlander, Ebbe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Re(3)(μ-H)(3)(C(25)H(22)P(2))(CO)(10)]·CH(2)Cl(2), the three Re atoms form a triangle bearing ten terminal carbonyl groups and three edge-bridging hydrides. The bis­(diphenyl­phosphan­yl)methane ligand bridges two Re atoms. Neglecting the Re—Re inter­actions, each Re atom is in a slightly distorted octa­hedral coordination environment. The dichloro­methane solvent mol­ecule is disordered over two sets of sites with fixed occupancies of 0.6 and 0.4. International Union of Crystallography 2011-11-25 /pmc/articles/PMC3238719/ /pubmed/22199596 http://dx.doi.org/10.1107/S1600536811049312 Text en © Abdel-Magied et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Abdel-Magied, Ahmed F.
Singh, Amrendra K.
Haukka, Matti
Nordlander, Ebbe
[μ-Bis(diphenyl­phosphan­yl-κP)methane]­deca­carbonyl­tri-μ-hydrido-trirhenium(I)(3 Re—Re) dichloromethane solvate
title [μ-Bis(diphenyl­phosphan­yl-κP)methane]­deca­carbonyl­tri-μ-hydrido-trirhenium(I)(3 Re—Re) dichloromethane solvate
title_full [μ-Bis(diphenyl­phosphan­yl-κP)methane]­deca­carbonyl­tri-μ-hydrido-trirhenium(I)(3 Re—Re) dichloromethane solvate
title_fullStr [μ-Bis(diphenyl­phosphan­yl-κP)methane]­deca­carbonyl­tri-μ-hydrido-trirhenium(I)(3 Re—Re) dichloromethane solvate
title_full_unstemmed [μ-Bis(diphenyl­phosphan­yl-κP)methane]­deca­carbonyl­tri-μ-hydrido-trirhenium(I)(3 Re—Re) dichloromethane solvate
title_short [μ-Bis(diphenyl­phosphan­yl-κP)methane]­deca­carbonyl­tri-μ-hydrido-trirhenium(I)(3 Re—Re) dichloromethane solvate
title_sort [μ-bis(diphenyl­phosphan­yl-κp)methane]­deca­carbonyl­tri-μ-hydrido-trirhenium(i)(3 re—re) dichloromethane solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238719/
https://www.ncbi.nlm.nih.gov/pubmed/22199596
http://dx.doi.org/10.1107/S1600536811049312
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AT haukkamatti mbisdiphenylphosphanylkpmethanedecacarbonyltrimhydridotrirheniumi3reredichloromethanesolvate
AT nordlanderebbe mbisdiphenylphosphanylkpmethanedecacarbonyltrimhydridotrirheniumi3reredichloromethanesolvate

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