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trans-Bromido(pyrimidinyl-κC (5))bis(triphenylphosphane-κP)palladium(II)
In the title complex, [PdBr(C(4)H(3)N(2))(C(18)H(15)P)(2)], the geometry around the Pd atom is distorted square-planar with the Pd atom displaced by 0.0334 (14) Å from the BrP(2)C plane. The two Ph(3)P ligands are in trans positions, defining a P—Pd—P angle of 171.78 (5)°, while the pyrimidinyl and...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238722/ https://www.ncbi.nlm.nih.gov/pubmed/22199599 http://dx.doi.org/10.1107/S1600536811049348 |
| _version_ | 1782219043729571840 |
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| author | Wang, Hsiao-Fen Zeng, Weng-Feng Lee, Gene-Hsiang Yih, Kuang-Hway |
| author_facet | Wang, Hsiao-Fen Zeng, Weng-Feng Lee, Gene-Hsiang Yih, Kuang-Hway |
| author_sort | Wang, Hsiao-Fen |
| collection | PubMed |
| description | In the title complex, [PdBr(C(4)H(3)N(2))(C(18)H(15)P)(2)], the geometry around the Pd atom is distorted square-planar with the Pd atom displaced by 0.0334 (14) Å from the BrP(2)C plane. The two Ph(3)P ligands are in trans positions, defining a P—Pd—P angle of 171.78 (5)°, while the pyrimidinyl and bromide ligands are trans to each other [C—Pd—Br = 174.63 (14)°]. |
| format | Online Article Text |
| id | pubmed-3238722 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32387222011-12-23 trans-Bromido(pyrimidinyl-κC (5))bis(triphenylphosphane-κP)palladium(II) Wang, Hsiao-Fen Zeng, Weng-Feng Lee, Gene-Hsiang Yih, Kuang-Hway Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [PdBr(C(4)H(3)N(2))(C(18)H(15)P)(2)], the geometry around the Pd atom is distorted square-planar with the Pd atom displaced by 0.0334 (14) Å from the BrP(2)C plane. The two Ph(3)P ligands are in trans positions, defining a P—Pd—P angle of 171.78 (5)°, while the pyrimidinyl and bromide ligands are trans to each other [C—Pd—Br = 174.63 (14)°]. International Union of Crystallography 2011-11-25 /pmc/articles/PMC3238722/ /pubmed/22199599 http://dx.doi.org/10.1107/S1600536811049348 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Hsiao-Fen Zeng, Weng-Feng Lee, Gene-Hsiang Yih, Kuang-Hway trans-Bromido(pyrimidinyl-κC (5))bis(triphenylphosphane-κP)palladium(II) |
| title |
trans-Bromido(pyrimidinyl-κC
(5))bis(triphenylphosphane-κP)palladium(II) |
| title_full |
trans-Bromido(pyrimidinyl-κC
(5))bis(triphenylphosphane-κP)palladium(II) |
| title_fullStr |
trans-Bromido(pyrimidinyl-κC
(5))bis(triphenylphosphane-κP)palladium(II) |
| title_full_unstemmed |
trans-Bromido(pyrimidinyl-κC
(5))bis(triphenylphosphane-κP)palladium(II) |
| title_short |
trans-Bromido(pyrimidinyl-κC
(5))bis(triphenylphosphane-κP)palladium(II) |
| title_sort | trans-bromido(pyrimidinyl-κc
(5))bis(triphenylphosphane-κp)palladium(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238722/ https://www.ncbi.nlm.nih.gov/pubmed/22199599 http://dx.doi.org/10.1107/S1600536811049348 |
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