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[S-Allyl-4-(4-hy­droxy-2-oxidobenzyl­idene-κO)-1-(2-oxidobenzyl­idene-κO)isothio­semicarbazidato-κ(2) N (1),N (4)](ethanol-κO)dioxido­uranium(VI) ethanol monosolvate

In the title compound, [U(C(18)H(15)N(3)O(3)S)O(2)(C(2)H(5)OH)]·C(2)H(5)OH, the U(VI) ion is in a distorted penta­gonal–bipyramidal coordination geometry, with two oxide O atoms in axial sites. Two N and two O atoms of the tetra­dentate ligand and an O atom of an ethanol ligand form the equatorial p...

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Detalles Bibliográficos
Autores principales: Takjoo, Reza, Dutkiewicz, Grzegorz, Kubicki, Maciej
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238725/
https://www.ncbi.nlm.nih.gov/pubmed/22199602
http://dx.doi.org/10.1107/S1600536811049579
Descripción
Sumario:In the title compound, [U(C(18)H(15)N(3)O(3)S)O(2)(C(2)H(5)OH)]·C(2)H(5)OH, the U(VI) ion is in a distorted penta­gonal–bipyramidal coordination geometry, with two oxide O atoms in axial sites. Two N and two O atoms of the tetra­dentate ligand and an O atom of an ethanol ligand form the equatorial plane. The dihedral angle between the mean planes of the two benzene rings is 34.8 (3)°. In the crystal, relatively strong O—H⋯O hydrogen bonds connect the complex and ethanol solvent mol­ecules into alternating centrosymmetric R (2) (2)(8) and R (4) (4)(16) ring motifs, forming chains along [100]. Weak inter­molecular C—H⋯O hydrogen bonds are also present.