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[S-Allyl-4-(4-hydroxy-2-oxidobenzylidene-κO)-1-(2-oxidobenzylidene-κO)isothiosemicarbazidato-κ(2) N (1),N (4)](ethanol-κO)dioxidouranium(VI) ethanol monosolvate
In the title compound, [U(C(18)H(15)N(3)O(3)S)O(2)(C(2)H(5)OH)]·C(2)H(5)OH, the U(VI) ion is in a distorted pentagonal–bipyramidal coordination geometry, with two oxide O atoms in axial sites. Two N and two O atoms of the tetradentate ligand and an O atom of an ethanol ligand form the equatorial p...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238725/ https://www.ncbi.nlm.nih.gov/pubmed/22199602 http://dx.doi.org/10.1107/S1600536811049579 |
Sumario: | In the title compound, [U(C(18)H(15)N(3)O(3)S)O(2)(C(2)H(5)OH)]·C(2)H(5)OH, the U(VI) ion is in a distorted pentagonal–bipyramidal coordination geometry, with two oxide O atoms in axial sites. Two N and two O atoms of the tetradentate ligand and an O atom of an ethanol ligand form the equatorial plane. The dihedral angle between the mean planes of the two benzene rings is 34.8 (3)°. In the crystal, relatively strong O—H⋯O hydrogen bonds connect the complex and ethanol solvent molecules into alternating centrosymmetric R (2) (2)(8) and R (4) (4)(16) ring motifs, forming chains along [100]. Weak intermolecular C—H⋯O hydrogen bonds are also present. |
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