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Diaquabis(4,4′-bipyridine-κN)bis(2,4,5-trifluoro-3-hydroxybenzoato-κO (1))manganese(II)
In the title compound, [Mn(C(7)H(2)F(3)O(3))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], the Mn(II) ion, situated on a centre of inversion, has a distorted octahedral coordination geometry and is coordinated by two N atoms from two 4,4′-bipyridine ligands, two O atoms from two 2,4,5-trifluoro-3-hydroxybenzo...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238726/ https://www.ncbi.nlm.nih.gov/pubmed/22199603 http://dx.doi.org/10.1107/S1600536811049610 |
Sumario: | In the title compound, [Mn(C(7)H(2)F(3)O(3))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], the Mn(II) ion, situated on a centre of inversion, has a distorted octahedral coordination geometry and is coordinated by two N atoms from two 4,4′-bipyridine ligands, two O atoms from two 2,4,5-trifluoro-3-hydroxybenzoate ligands and two water molecules. Intermolecular O—H⋯N hydrogen bonds link the molecules into a chain along the a axis. Interactions between neighboring chains occur through O—H⋯O hydrogen bonds, which link the chains into a two-dimensional supramolecular network parallel to the ac plane. In addition, O—H⋯O hydrogen bonds between the water molecules and carboxylate groups also exist in the the crystal structure. |
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