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Diaqua­bis­(4,4′-bipyridine-κN)bis­(2,4,5-trifluoro-3-hy­droxy­benzoato-κO (1))manganese(II)

In the title compound, [Mn(C(7)H(2)F(3)O(3))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], the Mn(II) ion, situated on a centre of inversion, has a distorted octa­hedral coordination geometry and is coordinated by two N atoms from two 4,4′-bipyridine ligands, two O atoms from two 2,4,5-trifluoro-3-hy­droxy­benzo...

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Detalles Bibliográficos
Autores principales: Min, Chun-Gang, Yang, Xi-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238726/
https://www.ncbi.nlm.nih.gov/pubmed/22199603
http://dx.doi.org/10.1107/S1600536811049610
Descripción
Sumario:In the title compound, [Mn(C(7)H(2)F(3)O(3))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], the Mn(II) ion, situated on a centre of inversion, has a distorted octa­hedral coordination geometry and is coordinated by two N atoms from two 4,4′-bipyridine ligands, two O atoms from two 2,4,5-trifluoro-3-hy­droxy­benzoate ligands and two water mol­ecules. Inter­molecular O—H⋯N hydrogen bonds link the mol­ecules into a chain along the a axis. Inter­actions between neighboring chains occur through O—H⋯O hydrogen bonds, which link the chains into a two-dimensional supra­molecular network parallel to the ac plane. In addition, O—H⋯O hydrogen bonds between the water mol­ecules and carboxyl­ate groups also exist in the the crystal structure.