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Diaquabis(4,4′-bipyridine-κN)bis(2,4,5-trifluoro-3-hydroxybenzoato-κO (1))manganese(II)
In the title compound, [Mn(C(7)H(2)F(3)O(3))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], the Mn(II) ion, situated on a centre of inversion, has a distorted octahedral coordination geometry and is coordinated by two N atoms from two 4,4′-bipyridine ligands, two O atoms from two 2,4,5-trifluoro-3-hydroxybenzo...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238726/ https://www.ncbi.nlm.nih.gov/pubmed/22199603 http://dx.doi.org/10.1107/S1600536811049610 |
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author | Min, Chun-Gang Yang, Xi-Kun |
author_facet | Min, Chun-Gang Yang, Xi-Kun |
author_sort | Min, Chun-Gang |
collection | PubMed |
description | In the title compound, [Mn(C(7)H(2)F(3)O(3))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], the Mn(II) ion, situated on a centre of inversion, has a distorted octahedral coordination geometry and is coordinated by two N atoms from two 4,4′-bipyridine ligands, two O atoms from two 2,4,5-trifluoro-3-hydroxybenzoate ligands and two water molecules. Intermolecular O—H⋯N hydrogen bonds link the molecules into a chain along the a axis. Interactions between neighboring chains occur through O—H⋯O hydrogen bonds, which link the chains into a two-dimensional supramolecular network parallel to the ac plane. In addition, O—H⋯O hydrogen bonds between the water molecules and carboxylate groups also exist in the the crystal structure. |
format | Online Article Text |
id | pubmed-3238726 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32387262011-12-23 Diaquabis(4,4′-bipyridine-κN)bis(2,4,5-trifluoro-3-hydroxybenzoato-κO (1))manganese(II) Min, Chun-Gang Yang, Xi-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(7)H(2)F(3)O(3))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], the Mn(II) ion, situated on a centre of inversion, has a distorted octahedral coordination geometry and is coordinated by two N atoms from two 4,4′-bipyridine ligands, two O atoms from two 2,4,5-trifluoro-3-hydroxybenzoate ligands and two water molecules. Intermolecular O—H⋯N hydrogen bonds link the molecules into a chain along the a axis. Interactions between neighboring chains occur through O—H⋯O hydrogen bonds, which link the chains into a two-dimensional supramolecular network parallel to the ac plane. In addition, O—H⋯O hydrogen bonds between the water molecules and carboxylate groups also exist in the the crystal structure. International Union of Crystallography 2011-11-25 /pmc/articles/PMC3238726/ /pubmed/22199603 http://dx.doi.org/10.1107/S1600536811049610 Text en © Min and Yang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Min, Chun-Gang Yang, Xi-Kun Diaquabis(4,4′-bipyridine-κN)bis(2,4,5-trifluoro-3-hydroxybenzoato-κO (1))manganese(II) |
title | Diaquabis(4,4′-bipyridine-κN)bis(2,4,5-trifluoro-3-hydroxybenzoato-κO
(1))manganese(II) |
title_full | Diaquabis(4,4′-bipyridine-κN)bis(2,4,5-trifluoro-3-hydroxybenzoato-κO
(1))manganese(II) |
title_fullStr | Diaquabis(4,4′-bipyridine-κN)bis(2,4,5-trifluoro-3-hydroxybenzoato-κO
(1))manganese(II) |
title_full_unstemmed | Diaquabis(4,4′-bipyridine-κN)bis(2,4,5-trifluoro-3-hydroxybenzoato-κO
(1))manganese(II) |
title_short | Diaquabis(4,4′-bipyridine-κN)bis(2,4,5-trifluoro-3-hydroxybenzoato-κO
(1))manganese(II) |
title_sort | diaquabis(4,4′-bipyridine-κn)bis(2,4,5-trifluoro-3-hydroxybenzoato-κo
(1))manganese(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238726/ https://www.ncbi.nlm.nih.gov/pubmed/22199603 http://dx.doi.org/10.1107/S1600536811049610 |
work_keys_str_mv | AT minchungang diaquabis44bipyridineknbis245trifluoro3hydroxybenzoatoko1manganeseii AT yangxikun diaquabis44bipyridineknbis245trifluoro3hydroxybenzoatoko1manganeseii |