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Diaqua­bis­(4,4′-bipyridine-κN)bis­(2,4,5-trifluoro-3-hy­droxy­benzoato-κO (1))manganese(II)

In the title compound, [Mn(C(7)H(2)F(3)O(3))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], the Mn(II) ion, situated on a centre of inversion, has a distorted octa­hedral coordination geometry and is coordinated by two N atoms from two 4,4′-bipyridine ligands, two O atoms from two 2,4,5-trifluoro-3-hy­droxy­benzo...

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Detalles Bibliográficos
Autores principales: Min, Chun-Gang, Yang, Xi-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238726/
https://www.ncbi.nlm.nih.gov/pubmed/22199603
http://dx.doi.org/10.1107/S1600536811049610
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author Min, Chun-Gang
Yang, Xi-Kun
author_facet Min, Chun-Gang
Yang, Xi-Kun
author_sort Min, Chun-Gang
collection PubMed
description In the title compound, [Mn(C(7)H(2)F(3)O(3))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], the Mn(II) ion, situated on a centre of inversion, has a distorted octa­hedral coordination geometry and is coordinated by two N atoms from two 4,4′-bipyridine ligands, two O atoms from two 2,4,5-trifluoro-3-hy­droxy­benzoate ligands and two water mol­ecules. Inter­molecular O—H⋯N hydrogen bonds link the mol­ecules into a chain along the a axis. Inter­actions between neighboring chains occur through O—H⋯O hydrogen bonds, which link the chains into a two-dimensional supra­molecular network parallel to the ac plane. In addition, O—H⋯O hydrogen bonds between the water mol­ecules and carboxyl­ate groups also exist in the the crystal structure.
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spelling pubmed-32387262011-12-23 Diaqua­bis­(4,4′-bipyridine-κN)bis­(2,4,5-trifluoro-3-hy­droxy­benzoato-κO (1))manganese(II) Min, Chun-Gang Yang, Xi-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(7)H(2)F(3)O(3))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], the Mn(II) ion, situated on a centre of inversion, has a distorted octa­hedral coordination geometry and is coordinated by two N atoms from two 4,4′-bipyridine ligands, two O atoms from two 2,4,5-trifluoro-3-hy­droxy­benzoate ligands and two water mol­ecules. Inter­molecular O—H⋯N hydrogen bonds link the mol­ecules into a chain along the a axis. Inter­actions between neighboring chains occur through O—H⋯O hydrogen bonds, which link the chains into a two-dimensional supra­molecular network parallel to the ac plane. In addition, O—H⋯O hydrogen bonds between the water mol­ecules and carboxyl­ate groups also exist in the the crystal structure. International Union of Crystallography 2011-11-25 /pmc/articles/PMC3238726/ /pubmed/22199603 http://dx.doi.org/10.1107/S1600536811049610 Text en © Min and Yang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Min, Chun-Gang
Yang, Xi-Kun
Diaqua­bis­(4,4′-bipyridine-κN)bis­(2,4,5-trifluoro-3-hy­droxy­benzoato-κO (1))manganese(II)
title Diaqua­bis­(4,4′-bipyridine-κN)bis­(2,4,5-trifluoro-3-hy­droxy­benzoato-κO (1))manganese(II)
title_full Diaqua­bis­(4,4′-bipyridine-κN)bis­(2,4,5-trifluoro-3-hy­droxy­benzoato-κO (1))manganese(II)
title_fullStr Diaqua­bis­(4,4′-bipyridine-κN)bis­(2,4,5-trifluoro-3-hy­droxy­benzoato-κO (1))manganese(II)
title_full_unstemmed Diaqua­bis­(4,4′-bipyridine-κN)bis­(2,4,5-trifluoro-3-hy­droxy­benzoato-κO (1))manganese(II)
title_short Diaqua­bis­(4,4′-bipyridine-κN)bis­(2,4,5-trifluoro-3-hy­droxy­benzoato-κO (1))manganese(II)
title_sort diaqua­bis­(4,4′-bipyridine-κn)bis­(2,4,5-trifluoro-3-hy­droxy­benzoato-κo (1))manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238726/
https://www.ncbi.nlm.nih.gov/pubmed/22199603
http://dx.doi.org/10.1107/S1600536811049610
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