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Bis[2-(2H-benzotriazol-2-yl)-4-methyl-6-(phenyliminomethyl-κN)phenolato-κO]palladium(II)
In the title complex, [Pd(C(20)H(15)N(4)O)(2)], the Pd(II) atom is tetracoordinated by two N atoms and two O atoms from two bidentate imine–benzotriazole phenolate ligands, forming a square-planar environment. The asymmetric unit contains two half-molecules in both of which the Pd(II) atom lies on...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238730/ https://www.ncbi.nlm.nih.gov/pubmed/22199607 http://dx.doi.org/10.1107/S1600536811049555 |
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author | Su, Jing-Kai Li, Chen-Yu Ko, Bao-Tsan |
author_facet | Su, Jing-Kai Li, Chen-Yu Ko, Bao-Tsan |
author_sort | Su, Jing-Kai |
collection | PubMed |
description | In the title complex, [Pd(C(20)H(15)N(4)O)(2)], the Pd(II) atom is tetracoordinated by two N atoms and two O atoms from two bidentate imine–benzotriazole phenolate ligands, forming a square-planar environment. The asymmetric unit contains two half-molecules in both of which the Pd(II) atom lies on a centre of symmetry. The average distances between the Pd(II) atom and the coordinated O and N atoms are 1.9831 (12) and 2.012 (2) Å, respectively. |
format | Online Article Text |
id | pubmed-3238730 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32387302011-12-23 Bis[2-(2H-benzotriazol-2-yl)-4-methyl-6-(phenyliminomethyl-κN)phenolato-κO]palladium(II) Su, Jing-Kai Li, Chen-Yu Ko, Bao-Tsan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Pd(C(20)H(15)N(4)O)(2)], the Pd(II) atom is tetracoordinated by two N atoms and two O atoms from two bidentate imine–benzotriazole phenolate ligands, forming a square-planar environment. The asymmetric unit contains two half-molecules in both of which the Pd(II) atom lies on a centre of symmetry. The average distances between the Pd(II) atom and the coordinated O and N atoms are 1.9831 (12) and 2.012 (2) Å, respectively. International Union of Crystallography 2011-11-25 /pmc/articles/PMC3238730/ /pubmed/22199607 http://dx.doi.org/10.1107/S1600536811049555 Text en © Su et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Su, Jing-Kai Li, Chen-Yu Ko, Bao-Tsan Bis[2-(2H-benzotriazol-2-yl)-4-methyl-6-(phenyliminomethyl-κN)phenolato-κO]palladium(II) |
title | Bis[2-(2H-benzotriazol-2-yl)-4-methyl-6-(phenyliminomethyl-κN)phenolato-κO]palladium(II) |
title_full | Bis[2-(2H-benzotriazol-2-yl)-4-methyl-6-(phenyliminomethyl-κN)phenolato-κO]palladium(II) |
title_fullStr | Bis[2-(2H-benzotriazol-2-yl)-4-methyl-6-(phenyliminomethyl-κN)phenolato-κO]palladium(II) |
title_full_unstemmed | Bis[2-(2H-benzotriazol-2-yl)-4-methyl-6-(phenyliminomethyl-κN)phenolato-κO]palladium(II) |
title_short | Bis[2-(2H-benzotriazol-2-yl)-4-methyl-6-(phenyliminomethyl-κN)phenolato-κO]palladium(II) |
title_sort | bis[2-(2h-benzotriazol-2-yl)-4-methyl-6-(phenyliminomethyl-κn)phenolato-κo]palladium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238730/ https://www.ncbi.nlm.nih.gov/pubmed/22199607 http://dx.doi.org/10.1107/S1600536811049555 |
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