catena-Poly[[bis­[3-(1H-imidazol-1-yl)-1-phenyl­propan-1-one-κN (3)]nickel(II)]-μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)]

In the title compound, [Ni(C(2)O(4))(C(12)H(12)N(2)O)(2)](n), the Ni(II) atom, lying on a twofold rotation axis, is coordinated by two N atoms from two monodentate 3-(1H-imidazol-1-yl)-1-phenyl­propan-1-one (L) ligands and four O atoms from two oxalate anions in a distorted octa­hedral geometry. The...

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Detalles Bibliográficos
Autor principal: Guo, Jian-Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238731/
https://www.ncbi.nlm.nih.gov/pubmed/22199608
http://dx.doi.org/10.1107/S1600536811049646
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author Guo, Jian-Hua
author_facet Guo, Jian-Hua
author_sort Guo, Jian-Hua
collection PubMed
description In the title compound, [Ni(C(2)O(4))(C(12)H(12)N(2)O)(2)](n), the Ni(II) atom, lying on a twofold rotation axis, is coordinated by two N atoms from two monodentate 3-(1H-imidazol-1-yl)-1-phenyl­propan-1-one (L) ligands and four O atoms from two oxalate anions in a distorted octa­hedral geometry. The oxalate anion has a twofold rotation axis through the mid-point of the C—C bond and acts as a bridging ligand, linking the Ni(II) atoms into a polymeric chain along [010]. Weak inter­molecular C—H⋯O hydrogen bonds connect the chains, resulting in a three-dimensional supra­molecular structure. >
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spelling pubmed-32387312011-12-23 catena-Poly[[bis­[3-(1H-imidazol-1-yl)-1-phenyl­propan-1-one-κN (3)]nickel(II)]-μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)] Guo, Jian-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(2)O(4))(C(12)H(12)N(2)O)(2)](n), the Ni(II) atom, lying on a twofold rotation axis, is coordinated by two N atoms from two monodentate 3-(1H-imidazol-1-yl)-1-phenyl­propan-1-one (L) ligands and four O atoms from two oxalate anions in a distorted octa­hedral geometry. The oxalate anion has a twofold rotation axis through the mid-point of the C—C bond and acts as a bridging ligand, linking the Ni(II) atoms into a polymeric chain along [010]. Weak inter­molecular C—H⋯O hydrogen bonds connect the chains, resulting in a three-dimensional supra­molecular structure. > International Union of Crystallography 2011-11-25 /pmc/articles/PMC3238731/ /pubmed/22199608 http://dx.doi.org/10.1107/S1600536811049646 Text en © Jian-Hua Guo 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Jian-Hua
catena-Poly[[bis­[3-(1H-imidazol-1-yl)-1-phenyl­propan-1-one-κN (3)]nickel(II)]-μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)]
title catena-Poly[[bis­[3-(1H-imidazol-1-yl)-1-phenyl­propan-1-one-κN (3)]nickel(II)]-μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)]
title_full catena-Poly[[bis­[3-(1H-imidazol-1-yl)-1-phenyl­propan-1-one-κN (3)]nickel(II)]-μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)]
title_fullStr catena-Poly[[bis­[3-(1H-imidazol-1-yl)-1-phenyl­propan-1-one-κN (3)]nickel(II)]-μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)]
title_full_unstemmed catena-Poly[[bis­[3-(1H-imidazol-1-yl)-1-phenyl­propan-1-one-κN (3)]nickel(II)]-μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)]
title_short catena-Poly[[bis­[3-(1H-imidazol-1-yl)-1-phenyl­propan-1-one-κN (3)]nickel(II)]-μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)]
title_sort catena-poly[[bis­[3-(1h-imidazol-1-yl)-1-phenyl­propan-1-one-κn (3)]nickel(ii)]-μ-oxalato-κ(4) o (1),o (2):o (1′),o (2′)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238731/
https://www.ncbi.nlm.nih.gov/pubmed/22199608
http://dx.doi.org/10.1107/S1600536811049646
work_keys_str_mv AT guojianhua catenapolybis31himidazol1yl1phenylpropan1onekn3nickeliimoxalatok4o1o2o1o2

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