Cargando…

Poly[(μ(4)-benzene-1,3,5-tricarboxyl­ato)bis­(dimethyl sulfoxide-κO)­neodymium(III)]

The asymmetric unit of the title compound, [Nd(C(9)H(3)O(6))(C(2)H(6)OS)(2)](n), contains one Nd(3+) ion, one benzene-1,3,5-tricarb­oxy­lic ligand and two coordinating dimethyl sulfoxide mol­ecules. The Nd(3+) ion is coordinated by six O atoms from four carboxyl­ate groups of the benzene-1,3,5-trica...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Zhongyue, Liu, Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238732/
https://www.ncbi.nlm.nih.gov/pubmed/22199609
http://dx.doi.org/10.1107/S1600536811049622
Descripción
Sumario:The asymmetric unit of the title compound, [Nd(C(9)H(3)O(6))(C(2)H(6)OS)(2)](n), contains one Nd(3+) ion, one benzene-1,3,5-tricarb­oxy­lic ligand and two coordinating dimethyl sulfoxide mol­ecules. The Nd(3+) ion is coordinated by six O atoms from four carboxyl­ate groups of the benzene-1,3,5-tricarboxyl­ate ligands and two O atoms from two dimethyl sulfoxide mol­ecules. The metal-organic cluster formed upon symmetry expansion of the asymmetric unit consists of two metal atoms and four benzene-1,3,5-tricarboxyl­ate groups, creating a paddle-wheel-type building block arrangement. The remaining coordination sites are occupied by additional benzene-1,3,5-tricarboxyl­ate groups and dimethyl sulfoxide mol­ecules, forming a three-dimensional polymeric rare earth metal-organic framework structure.