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Poly[(μ(4)-benzene-1,3,5-tricarboxylato)bis(dimethyl sulfoxide-κO)neodymium(III)]
The asymmetric unit of the title compound, [Nd(C(9)H(3)O(6))(C(2)H(6)OS)(2)](n), contains one Nd(3+) ion, one benzene-1,3,5-tricarboxylic ligand and two coordinating dimethyl sulfoxide molecules. The Nd(3+) ion is coordinated by six O atoms from four carboxylate groups of the benzene-1,3,5-trica...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238732/ https://www.ncbi.nlm.nih.gov/pubmed/22199609 http://dx.doi.org/10.1107/S1600536811049622 |
Sumario: | The asymmetric unit of the title compound, [Nd(C(9)H(3)O(6))(C(2)H(6)OS)(2)](n), contains one Nd(3+) ion, one benzene-1,3,5-tricarboxylic ligand and two coordinating dimethyl sulfoxide molecules. The Nd(3+) ion is coordinated by six O atoms from four carboxylate groups of the benzene-1,3,5-tricarboxylate ligands and two O atoms from two dimethyl sulfoxide molecules. The metal-organic cluster formed upon symmetry expansion of the asymmetric unit consists of two metal atoms and four benzene-1,3,5-tricarboxylate groups, creating a paddle-wheel-type building block arrangement. The remaining coordination sites are occupied by additional benzene-1,3,5-tricarboxylate groups and dimethyl sulfoxide molecules, forming a three-dimensional polymeric rare earth metal-organic framework structure. |
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