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Poly[(μ(4)-benzene-1,3,5-tricarboxylato)bis(dimethyl sulfoxide-κO)neodymium(III)]
The asymmetric unit of the title compound, [Nd(C(9)H(3)O(6))(C(2)H(6)OS)(2)](n), contains one Nd(3+) ion, one benzene-1,3,5-tricarboxylic ligand and two coordinating dimethyl sulfoxide molecules. The Nd(3+) ion is coordinated by six O atoms from four carboxylate groups of the benzene-1,3,5-trica...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238732/ https://www.ncbi.nlm.nih.gov/pubmed/22199609 http://dx.doi.org/10.1107/S1600536811049622 |
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author | Li, Zhongyue Liu, Kun |
author_facet | Li, Zhongyue Liu, Kun |
author_sort | Li, Zhongyue |
collection | PubMed |
description | The asymmetric unit of the title compound, [Nd(C(9)H(3)O(6))(C(2)H(6)OS)(2)](n), contains one Nd(3+) ion, one benzene-1,3,5-tricarboxylic ligand and two coordinating dimethyl sulfoxide molecules. The Nd(3+) ion is coordinated by six O atoms from four carboxylate groups of the benzene-1,3,5-tricarboxylate ligands and two O atoms from two dimethyl sulfoxide molecules. The metal-organic cluster formed upon symmetry expansion of the asymmetric unit consists of two metal atoms and four benzene-1,3,5-tricarboxylate groups, creating a paddle-wheel-type building block arrangement. The remaining coordination sites are occupied by additional benzene-1,3,5-tricarboxylate groups and dimethyl sulfoxide molecules, forming a three-dimensional polymeric rare earth metal-organic framework structure. |
format | Online Article Text |
id | pubmed-3238732 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32387322011-12-23 Poly[(μ(4)-benzene-1,3,5-tricarboxylato)bis(dimethyl sulfoxide-κO)neodymium(III)] Li, Zhongyue Liu, Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Nd(C(9)H(3)O(6))(C(2)H(6)OS)(2)](n), contains one Nd(3+) ion, one benzene-1,3,5-tricarboxylic ligand and two coordinating dimethyl sulfoxide molecules. The Nd(3+) ion is coordinated by six O atoms from four carboxylate groups of the benzene-1,3,5-tricarboxylate ligands and two O atoms from two dimethyl sulfoxide molecules. The metal-organic cluster formed upon symmetry expansion of the asymmetric unit consists of two metal atoms and four benzene-1,3,5-tricarboxylate groups, creating a paddle-wheel-type building block arrangement. The remaining coordination sites are occupied by additional benzene-1,3,5-tricarboxylate groups and dimethyl sulfoxide molecules, forming a three-dimensional polymeric rare earth metal-organic framework structure. International Union of Crystallography 2011-11-25 /pmc/articles/PMC3238732/ /pubmed/22199609 http://dx.doi.org/10.1107/S1600536811049622 Text en © Li and Liu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Zhongyue Liu, Kun Poly[(μ(4)-benzene-1,3,5-tricarboxylato)bis(dimethyl sulfoxide-κO)neodymium(III)] |
title | Poly[(μ(4)-benzene-1,3,5-tricarboxylato)bis(dimethyl sulfoxide-κO)neodymium(III)] |
title_full | Poly[(μ(4)-benzene-1,3,5-tricarboxylato)bis(dimethyl sulfoxide-κO)neodymium(III)] |
title_fullStr | Poly[(μ(4)-benzene-1,3,5-tricarboxylato)bis(dimethyl sulfoxide-κO)neodymium(III)] |
title_full_unstemmed | Poly[(μ(4)-benzene-1,3,5-tricarboxylato)bis(dimethyl sulfoxide-κO)neodymium(III)] |
title_short | Poly[(μ(4)-benzene-1,3,5-tricarboxylato)bis(dimethyl sulfoxide-κO)neodymium(III)] |
title_sort | poly[(μ(4)-benzene-1,3,5-tricarboxylato)bis(dimethyl sulfoxide-κo)neodymium(iii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238732/ https://www.ncbi.nlm.nih.gov/pubmed/22199609 http://dx.doi.org/10.1107/S1600536811049622 |
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