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Poly[(μ(4)-benzene-1,3,5-tricarboxyl­ato)bis­(dimethyl sulfoxide-κO)­neodymium(III)]

The asymmetric unit of the title compound, [Nd(C(9)H(3)O(6))(C(2)H(6)OS)(2)](n), contains one Nd(3+) ion, one benzene-1,3,5-tricarb­oxy­lic ligand and two coordinating dimethyl sulfoxide mol­ecules. The Nd(3+) ion is coordinated by six O atoms from four carboxyl­ate groups of the benzene-1,3,5-trica...

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Detalles Bibliográficos
Autores principales: Li, Zhongyue, Liu, Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238732/
https://www.ncbi.nlm.nih.gov/pubmed/22199609
http://dx.doi.org/10.1107/S1600536811049622
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author Li, Zhongyue
Liu, Kun
author_facet Li, Zhongyue
Liu, Kun
author_sort Li, Zhongyue
collection PubMed
description The asymmetric unit of the title compound, [Nd(C(9)H(3)O(6))(C(2)H(6)OS)(2)](n), contains one Nd(3+) ion, one benzene-1,3,5-tricarb­oxy­lic ligand and two coordinating dimethyl sulfoxide mol­ecules. The Nd(3+) ion is coordinated by six O atoms from four carboxyl­ate groups of the benzene-1,3,5-tricarboxyl­ate ligands and two O atoms from two dimethyl sulfoxide mol­ecules. The metal-organic cluster formed upon symmetry expansion of the asymmetric unit consists of two metal atoms and four benzene-1,3,5-tricarboxyl­ate groups, creating a paddle-wheel-type building block arrangement. The remaining coordination sites are occupied by additional benzene-1,3,5-tricarboxyl­ate groups and dimethyl sulfoxide mol­ecules, forming a three-dimensional polymeric rare earth metal-organic framework structure.
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spelling pubmed-32387322011-12-23 Poly[(μ(4)-benzene-1,3,5-tricarboxyl­ato)bis­(dimethyl sulfoxide-κO)­neodymium(III)] Li, Zhongyue Liu, Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Nd(C(9)H(3)O(6))(C(2)H(6)OS)(2)](n), contains one Nd(3+) ion, one benzene-1,3,5-tricarb­oxy­lic ligand and two coordinating dimethyl sulfoxide mol­ecules. The Nd(3+) ion is coordinated by six O atoms from four carboxyl­ate groups of the benzene-1,3,5-tricarboxyl­ate ligands and two O atoms from two dimethyl sulfoxide mol­ecules. The metal-organic cluster formed upon symmetry expansion of the asymmetric unit consists of two metal atoms and four benzene-1,3,5-tricarboxyl­ate groups, creating a paddle-wheel-type building block arrangement. The remaining coordination sites are occupied by additional benzene-1,3,5-tricarboxyl­ate groups and dimethyl sulfoxide mol­ecules, forming a three-dimensional polymeric rare earth metal-organic framework structure. International Union of Crystallography 2011-11-25 /pmc/articles/PMC3238732/ /pubmed/22199609 http://dx.doi.org/10.1107/S1600536811049622 Text en © Li and Liu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Zhongyue
Liu, Kun
Poly[(μ(4)-benzene-1,3,5-tricarboxyl­ato)bis­(dimethyl sulfoxide-κO)­neodymium(III)]
title Poly[(μ(4)-benzene-1,3,5-tricarboxyl­ato)bis­(dimethyl sulfoxide-κO)­neodymium(III)]
title_full Poly[(μ(4)-benzene-1,3,5-tricarboxyl­ato)bis­(dimethyl sulfoxide-κO)­neodymium(III)]
title_fullStr Poly[(μ(4)-benzene-1,3,5-tricarboxyl­ato)bis­(dimethyl sulfoxide-κO)­neodymium(III)]
title_full_unstemmed Poly[(μ(4)-benzene-1,3,5-tricarboxyl­ato)bis­(dimethyl sulfoxide-κO)­neodymium(III)]
title_short Poly[(μ(4)-benzene-1,3,5-tricarboxyl­ato)bis­(dimethyl sulfoxide-κO)­neodymium(III)]
title_sort poly[(μ(4)-benzene-1,3,5-tricarboxyl­ato)bis­(dimethyl sulfoxide-κo)­neodymium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238732/
https://www.ncbi.nlm.nih.gov/pubmed/22199609
http://dx.doi.org/10.1107/S1600536811049622
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