catena-Poly[[trimethyl­tin(IV)]-μ-5-methyl­thio­phene-2-carboxyl­ato-κ(2) O:O′]

In the title polymeric coordination compound, [Sn(CH(3))(3)(C(6)H(5)O(2)S)](n), which contains two formula units in the asymmetric unit, the Sn(IV) atom has a distorted trigonal–bipyramidal geometry, with two O atoms of the ligands in axial positions and three methyl groups in equatorial positions....

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Detalles Bibliográficos
Autores principales: Zhu, Qi, Zhang, Rufen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238733/
https://www.ncbi.nlm.nih.gov/pubmed/22199610
http://dx.doi.org/10.1107/S1600536811049713
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author Zhu, Qi
Zhang, Rufen
author_facet Zhu, Qi
Zhang, Rufen
author_sort Zhu, Qi
collection PubMed
description In the title polymeric coordination compound, [Sn(CH(3))(3)(C(6)H(5)O(2)S)](n), which contains two formula units in the asymmetric unit, the Sn(IV) atom has a distorted trigonal–bipyramidal geometry, with two O atoms of the ligands in axial positions and three methyl groups in equatorial positions. Adjacent Sn(IV) atoms are bridged by the ligands, thereby forming a chain propagating in [010].
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spelling pubmed-32387332011-12-23 catena-Poly[[trimethyl­tin(IV)]-μ-5-methyl­thio­phene-2-carboxyl­ato-κ(2) O:O′] Zhu, Qi Zhang, Rufen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymeric coordination compound, [Sn(CH(3))(3)(C(6)H(5)O(2)S)](n), which contains two formula units in the asymmetric unit, the Sn(IV) atom has a distorted trigonal–bipyramidal geometry, with two O atoms of the ligands in axial positions and three methyl groups in equatorial positions. Adjacent Sn(IV) atoms are bridged by the ligands, thereby forming a chain propagating in [010]. International Union of Crystallography 2011-11-25 /pmc/articles/PMC3238733/ /pubmed/22199610 http://dx.doi.org/10.1107/S1600536811049713 Text en © Zhu and Zhang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Qi
Zhang, Rufen
catena-Poly[[trimethyl­tin(IV)]-μ-5-methyl­thio­phene-2-carboxyl­ato-κ(2) O:O′]
title catena-Poly[[trimethyl­tin(IV)]-μ-5-methyl­thio­phene-2-carboxyl­ato-κ(2) O:O′]
title_full catena-Poly[[trimethyl­tin(IV)]-μ-5-methyl­thio­phene-2-carboxyl­ato-κ(2) O:O′]
title_fullStr catena-Poly[[trimethyl­tin(IV)]-μ-5-methyl­thio­phene-2-carboxyl­ato-κ(2) O:O′]
title_full_unstemmed catena-Poly[[trimethyl­tin(IV)]-μ-5-methyl­thio­phene-2-carboxyl­ato-κ(2) O:O′]
title_short catena-Poly[[trimethyl­tin(IV)]-μ-5-methyl­thio­phene-2-carboxyl­ato-κ(2) O:O′]
title_sort catena-poly[[trimethyl­tin(iv)]-μ-5-methyl­thio­phene-2-carboxyl­ato-κ(2) o:o′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238733/
https://www.ncbi.nlm.nih.gov/pubmed/22199610
http://dx.doi.org/10.1107/S1600536811049713
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