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Poly[[(μ(3)-5-aminoisophthalato-κ(3) O (1):O (3):N)(1H-imidazole-κN (3))zinc] 0.25-hydrate]
In the title coordination polymer, {[Zn(C(8)H(5)NO(4))(C(3)H(4)N(2))]·0.25H(2)O}(n), the Zn(2+) cation has an N(2)O(2) donor set involving two carboxylate O atoms from two 5-aminoisophthalate anions, one N atom from a 5-aminoisophthalate anion, and one imidazole N atom displaying a slightly disto...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238734/ https://www.ncbi.nlm.nih.gov/pubmed/22199611 http://dx.doi.org/10.1107/S1600536811050045 |
Sumario: | In the title coordination polymer, {[Zn(C(8)H(5)NO(4))(C(3)H(4)N(2))]·0.25H(2)O}(n), the Zn(2+) cation has an N(2)O(2) donor set involving two carboxylate O atoms from two 5-aminoisophthalate anions, one N atom from a 5-aminoisophthalate anion, and one imidazole N atom displaying a slightly distorted tetrahedral geometry with two additional O-atom neighbours, with Zn-to-ligand distances of 2.711 (2) and 2.717 (2) Å, respectively. Each 5-aminoisophthalate anion acts as a μ(3)-bridge linking symmetry-related Zn(II) ions into a layered polymeric structure parallel to (100). The asymmetric unit also comprises a disordered crystal water molecule located on an inversion centre with 0.25 occupancy. In the crystal, N—H⋯O hydrogen bonds form a three-dimensional network. |
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