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Poly[[(μ(3)-5-amino­isophthalato-κ(3) O (1):O (3):N)(1H-imidazole-κN (3))zinc] 0.25-hydrate]

In the title coordination polymer, {[Zn(C(8)H(5)NO(4))(C(3)H(4)N(2))]·0.25H(2)O}(n), the Zn(2+) cation has an N(2)O(2) donor set involving two carboxyl­ate O atoms from two 5-amino­isophthalate anions, one N atom from a 5-amino­isophthalate anion, and one imidazole N atom displaying a slightly disto...

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Detalles Bibliográficos
Autores principales: Kuai, Hai-Wei, Cheng, Xiao-Chun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238734/
https://www.ncbi.nlm.nih.gov/pubmed/22199611
http://dx.doi.org/10.1107/S1600536811050045
Descripción
Sumario:In the title coordination polymer, {[Zn(C(8)H(5)NO(4))(C(3)H(4)N(2))]·0.25H(2)O}(n), the Zn(2+) cation has an N(2)O(2) donor set involving two carboxyl­ate O atoms from two 5-amino­isophthalate anions, one N atom from a 5-amino­isophthalate anion, and one imidazole N atom displaying a slightly distorted tetra­hedral geometry with two additional O-atom neighbours, with Zn-to-ligand distances of 2.711 (2) and 2.717 (2) Å, respectively. Each 5-amino­isophthalate anion acts as a μ(3)-bridge linking symmetry-related Zn(II) ions into a layered polymeric structure parallel to (100). The asymmetric unit also comprises a disordered crystal water molecule located on an inversion centre with 0.25 occupancy. In the crystal, N—H⋯O hydrogen bonds form a three-dimensional network.