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(Acetonitrile-κN)chloridobis[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III)

The Ir(III) atom of the title compound, [Ir(C(11)H(8)N)(2)Cl(CH(3)CN)], displays a distorted octa­hedral coordination. The pyridyl groups are in trans positions [N—Ir—N = 173.07 (10)°], while the phenyl groups are trans with respect to the acetonitrile and chloride groups [C—Ir—N = 178.13 (11) and C...

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Detalles Bibliográficos
Autores principales: Blasberg, Florian, Bats, Jan W., Wagner, Matthias, Lerner, Hans-Wolfram
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238736/
https://www.ncbi.nlm.nih.gov/pubmed/22199613
http://dx.doi.org/10.1107/S1600536811049373
Descripción
Sumario:The Ir(III) atom of the title compound, [Ir(C(11)H(8)N)(2)Cl(CH(3)CN)], displays a distorted octa­hedral coordination. The pyridyl groups are in trans positions [N—Ir—N = 173.07 (10)°], while the phenyl groups are trans with respect to the acetonitrile and chloride groups [C—Ir—N = 178.13 (11) and C—Ir—Cl = 176.22 (9)°]. The pyridyl­phenyl groups only show a small deviation from planarity, with the dihedral angle between the planes of the two six-membered rings in each pyridyl­phenyl group being 5.6 (2) and 5.8 (1)°. The crystal packing shows inter­molecular C—H⋯Cl, C—H⋯π(acetonitrile) and C—H⋯π(pyridyl­phen­yl) contacts.