(Acetonitrile-κN)chloridobis[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III)

The Ir(III) atom of the title compound, [Ir(C(11)H(8)N)(2)Cl(CH(3)CN)], displays a distorted octa­hedral coordination. The pyridyl groups are in trans positions [N—Ir—N = 173.07 (10)°], while the phenyl groups are trans with respect to the acetonitrile and chloride groups [C—Ir—N = 178.13 (11) and C...

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Autores principales: Blasberg, Florian, Bats, Jan W., Wagner, Matthias, Lerner, Hans-Wolfram
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238736/
https://www.ncbi.nlm.nih.gov/pubmed/22199613
http://dx.doi.org/10.1107/S1600536811049373
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author Blasberg, Florian
Bats, Jan W.
Wagner, Matthias
Lerner, Hans-Wolfram
author_facet Blasberg, Florian
Bats, Jan W.
Wagner, Matthias
Lerner, Hans-Wolfram
author_sort Blasberg, Florian
collection PubMed
description The Ir(III) atom of the title compound, [Ir(C(11)H(8)N)(2)Cl(CH(3)CN)], displays a distorted octa­hedral coordination. The pyridyl groups are in trans positions [N—Ir—N = 173.07 (10)°], while the phenyl groups are trans with respect to the acetonitrile and chloride groups [C—Ir—N = 178.13 (11) and C—Ir—Cl = 176.22 (9)°]. The pyridyl­phenyl groups only show a small deviation from planarity, with the dihedral angle between the planes of the two six-membered rings in each pyridyl­phenyl group being 5.6 (2) and 5.8 (1)°. The crystal packing shows inter­molecular C—H⋯Cl, C—H⋯π(acetonitrile) and C—H⋯π(pyridyl­phen­yl) contacts.
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spelling pubmed-32387362011-12-23 (Acetonitrile-κN)chloridobis[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III) Blasberg, Florian Bats, Jan W. Wagner, Matthias Lerner, Hans-Wolfram Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ir(III) atom of the title compound, [Ir(C(11)H(8)N)(2)Cl(CH(3)CN)], displays a distorted octa­hedral coordination. The pyridyl groups are in trans positions [N—Ir—N = 173.07 (10)°], while the phenyl groups are trans with respect to the acetonitrile and chloride groups [C—Ir—N = 178.13 (11) and C—Ir—Cl = 176.22 (9)°]. The pyridyl­phenyl groups only show a small deviation from planarity, with the dihedral angle between the planes of the two six-membered rings in each pyridyl­phenyl group being 5.6 (2) and 5.8 (1)°. The crystal packing shows inter­molecular C—H⋯Cl, C—H⋯π(acetonitrile) and C—H⋯π(pyridyl­phen­yl) contacts. International Union of Crystallography 2011-11-25 /pmc/articles/PMC3238736/ /pubmed/22199613 http://dx.doi.org/10.1107/S1600536811049373 Text en © Blasberg et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Blasberg, Florian
Bats, Jan W.
Wagner, Matthias
Lerner, Hans-Wolfram
(Acetonitrile-κN)chloridobis[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III)
title (Acetonitrile-κN)chloridobis[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III)
title_full (Acetonitrile-κN)chloridobis[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III)
title_fullStr (Acetonitrile-κN)chloridobis[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III)
title_full_unstemmed (Acetonitrile-κN)chloridobis[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III)
title_short (Acetonitrile-κN)chloridobis[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III)
title_sort (acetonitrile-κn)chloridobis[2-(pyridin-2-yl)phenyl-κ(2) c (1),n]iridium(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238736/
https://www.ncbi.nlm.nih.gov/pubmed/22199613
http://dx.doi.org/10.1107/S1600536811049373
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AT wagnermatthias acetonitrileknchloridobis2pyridin2ylphenylk2c1niridiumiii
AT lernerhanswolfram acetonitrileknchloridobis2pyridin2ylphenylk2c1niridiumiii

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