4,5-Dihydro-3a,5a-diazo­niapyrene triiodidocuprate(I)

In the dianion of the title salt, (C(14)H(12)N(2))[CuI(3)], the Cu(I) atom is coordinated by three I(−) ions that define a nearly trigonal-planar geometry; the Cu(I) atom lies 0.1407 (6) Å out of the plane. With the exception of the methyl­ene C atoms, the dication is essentially planar (r.m.s devia...

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Detalles Bibliográficos
Autores principales: Wu, Di, Hao, Peng-Chao, Niu, Yun-Yin, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238737/
https://www.ncbi.nlm.nih.gov/pubmed/22199614
http://dx.doi.org/10.1107/S1600536811050136
Descripción
Sumario:In the dianion of the title salt, (C(14)H(12)N(2))[CuI(3)], the Cu(I) atom is coordinated by three I(−) ions that define a nearly trigonal-planar geometry; the Cu(I) atom lies 0.1407 (6) Å out of the plane. With the exception of the methyl­ene C atoms, the dication is essentially planar (r.m.s deviation = 0.067 Å). The most significant inter­action between the ions is a C—H⋯I contact.

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