4,5-Dihydro-3a,5a-diazo­niapyrene triiodidocuprate(I)

In the dianion of the title salt, (C(14)H(12)N(2))[CuI(3)], the Cu(I) atom is coordinated by three I(−) ions that define a nearly trigonal-planar geometry; the Cu(I) atom lies 0.1407 (6) Å out of the plane. With the exception of the methyl­ene C atoms, the dication is essentially planar (r.m.s devia...

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Detalles Bibliográficos
Autores principales: Wu, Di, Hao, Peng-Chao, Niu, Yun-Yin, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238737/
https://www.ncbi.nlm.nih.gov/pubmed/22199614
http://dx.doi.org/10.1107/S1600536811050136
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author Wu, Di
Hao, Peng-Chao
Niu, Yun-Yin
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Wu, Di
Hao, Peng-Chao
Niu, Yun-Yin
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Wu, Di
collection PubMed
description In the dianion of the title salt, (C(14)H(12)N(2))[CuI(3)], the Cu(I) atom is coordinated by three I(−) ions that define a nearly trigonal-planar geometry; the Cu(I) atom lies 0.1407 (6) Å out of the plane. With the exception of the methyl­ene C atoms, the dication is essentially planar (r.m.s deviation = 0.067 Å). The most significant inter­action between the ions is a C—H⋯I contact.
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spelling pubmed-32387372011-12-23 4,5-Dihydro-3a,5a-diazo­niapyrene triiodidocuprate(I) Wu, Di Hao, Peng-Chao Niu, Yun-Yin Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the dianion of the title salt, (C(14)H(12)N(2))[CuI(3)], the Cu(I) atom is coordinated by three I(−) ions that define a nearly trigonal-planar geometry; the Cu(I) atom lies 0.1407 (6) Å out of the plane. With the exception of the methyl­ene C atoms, the dication is essentially planar (r.m.s deviation = 0.067 Å). The most significant inter­action between the ions is a C—H⋯I contact. International Union of Crystallography 2011-11-25 /pmc/articles/PMC3238737/ /pubmed/22199614 http://dx.doi.org/10.1107/S1600536811050136 Text en © Wu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Di
Hao, Peng-Chao
Niu, Yun-Yin
Ng, Seik Weng
Tiekink, Edward R. T.
4,5-Dihydro-3a,5a-diazo­niapyrene triiodidocuprate(I)
title 4,5-Dihydro-3a,5a-diazo­niapyrene triiodidocuprate(I)
title_full 4,5-Dihydro-3a,5a-diazo­niapyrene triiodidocuprate(I)
title_fullStr 4,5-Dihydro-3a,5a-diazo­niapyrene triiodidocuprate(I)
title_full_unstemmed 4,5-Dihydro-3a,5a-diazo­niapyrene triiodidocuprate(I)
title_short 4,5-Dihydro-3a,5a-diazo­niapyrene triiodidocuprate(I)
title_sort 4,5-dihydro-3a,5a-diazo­niapyrene triiodidocuprate(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238737/
https://www.ncbi.nlm.nih.gov/pubmed/22199614
http://dx.doi.org/10.1107/S1600536811050136
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