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Tetra­kis(μ(2)-ferrocene­carboxyl­ato-κ(2) O:O′)bis­[(methanol-κO)copper(II)] methanol disolvate

The complex mol­ecule of the title compound, [Cu(2)Fe(4)(C(5)H(5))(4)(C(6)H(4)O(2))(4)(CH(3)OH)(2)]·2CH(3)OH, lies about an inversion centre and contains two centrosymetrically related Cu(II) atoms bridged by four O:O′-bidentante ferrocene­carboxyl­ate anions, leading to a dimeric tetra­bridged unit...

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Detalles Bibliográficos
Autores principales: Artetxe, Beñat, Vitoria, Pablo, Pache, Aroa, Reinoso, Santiago, Gutiérrez-Zorrilla, Juan M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238738/
https://www.ncbi.nlm.nih.gov/pubmed/22199615
http://dx.doi.org/10.1107/S1600536811050185
Descripción
Sumario:The complex mol­ecule of the title compound, [Cu(2)Fe(4)(C(5)H(5))(4)(C(6)H(4)O(2))(4)(CH(3)OH)(2)]·2CH(3)OH, lies about an inversion centre and contains two centrosymetrically related Cu(II) atoms bridged by four O:O′-bidentante ferrocene­carboxyl­ate anions, leading to a dimeric tetra­bridged unit with a paddle-wheel geometry. The Cu(II) atom has a distorted square-pyramidal coordination environment with four O atoms from four ferrocene­carboxyl­ate ligands in basal positions and an O atom from a methanol mol­ecule in an apical position. One of the two crystallographically independent ferrocenyl groups has a staggered conformation, while the other is eclipsed. The mol­ecules are connected into a chain along the b axis by O—H⋯O hydrogen bonds involving coordinated and uncoordinated methanol mol­ecules and the O atom from a ferrocene­carboxyl­ate unit.