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Tetrakis(μ(2)-ferrocenecarboxylato-κ(2) O:O′)bis[(methanol-κO)copper(II)] methanol disolvate
The complex molecule of the title compound, [Cu(2)Fe(4)(C(5)H(5))(4)(C(6)H(4)O(2))(4)(CH(3)OH)(2)]·2CH(3)OH, lies about an inversion centre and contains two centrosymetrically related Cu(II) atoms bridged by four O:O′-bidentante ferrocenecarboxylate anions, leading to a dimeric tetrabridged unit...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238738/ https://www.ncbi.nlm.nih.gov/pubmed/22199615 http://dx.doi.org/10.1107/S1600536811050185 |
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author | Artetxe, Beñat Vitoria, Pablo Pache, Aroa Reinoso, Santiago Gutiérrez-Zorrilla, Juan M. |
author_facet | Artetxe, Beñat Vitoria, Pablo Pache, Aroa Reinoso, Santiago Gutiérrez-Zorrilla, Juan M. |
author_sort | Artetxe, Beñat |
collection | PubMed |
description | The complex molecule of the title compound, [Cu(2)Fe(4)(C(5)H(5))(4)(C(6)H(4)O(2))(4)(CH(3)OH)(2)]·2CH(3)OH, lies about an inversion centre and contains two centrosymetrically related Cu(II) atoms bridged by four O:O′-bidentante ferrocenecarboxylate anions, leading to a dimeric tetrabridged unit with a paddle-wheel geometry. The Cu(II) atom has a distorted square-pyramidal coordination environment with four O atoms from four ferrocenecarboxylate ligands in basal positions and an O atom from a methanol molecule in an apical position. One of the two crystallographically independent ferrocenyl groups has a staggered conformation, while the other is eclipsed. The molecules are connected into a chain along the b axis by O—H⋯O hydrogen bonds involving coordinated and uncoordinated methanol molecules and the O atom from a ferrocenecarboxylate unit. |
format | Online Article Text |
id | pubmed-3238738 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32387382011-12-23 Tetrakis(μ(2)-ferrocenecarboxylato-κ(2) O:O′)bis[(methanol-κO)copper(II)] methanol disolvate Artetxe, Beñat Vitoria, Pablo Pache, Aroa Reinoso, Santiago Gutiérrez-Zorrilla, Juan M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complex molecule of the title compound, [Cu(2)Fe(4)(C(5)H(5))(4)(C(6)H(4)O(2))(4)(CH(3)OH)(2)]·2CH(3)OH, lies about an inversion centre and contains two centrosymetrically related Cu(II) atoms bridged by four O:O′-bidentante ferrocenecarboxylate anions, leading to a dimeric tetrabridged unit with a paddle-wheel geometry. The Cu(II) atom has a distorted square-pyramidal coordination environment with four O atoms from four ferrocenecarboxylate ligands in basal positions and an O atom from a methanol molecule in an apical position. One of the two crystallographically independent ferrocenyl groups has a staggered conformation, while the other is eclipsed. The molecules are connected into a chain along the b axis by O—H⋯O hydrogen bonds involving coordinated and uncoordinated methanol molecules and the O atom from a ferrocenecarboxylate unit. International Union of Crystallography 2011-11-25 /pmc/articles/PMC3238738/ /pubmed/22199615 http://dx.doi.org/10.1107/S1600536811050185 Text en © Artetxe et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Artetxe, Beñat Vitoria, Pablo Pache, Aroa Reinoso, Santiago Gutiérrez-Zorrilla, Juan M. Tetrakis(μ(2)-ferrocenecarboxylato-κ(2) O:O′)bis[(methanol-κO)copper(II)] methanol disolvate |
title | Tetrakis(μ(2)-ferrocenecarboxylato-κ(2)
O:O′)bis[(methanol-κO)copper(II)] methanol disolvate |
title_full | Tetrakis(μ(2)-ferrocenecarboxylato-κ(2)
O:O′)bis[(methanol-κO)copper(II)] methanol disolvate |
title_fullStr | Tetrakis(μ(2)-ferrocenecarboxylato-κ(2)
O:O′)bis[(methanol-κO)copper(II)] methanol disolvate |
title_full_unstemmed | Tetrakis(μ(2)-ferrocenecarboxylato-κ(2)
O:O′)bis[(methanol-κO)copper(II)] methanol disolvate |
title_short | Tetrakis(μ(2)-ferrocenecarboxylato-κ(2)
O:O′)bis[(methanol-κO)copper(II)] methanol disolvate |
title_sort | tetrakis(μ(2)-ferrocenecarboxylato-κ(2)
o:o′)bis[(methanol-κo)copper(ii)] methanol disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238738/ https://www.ncbi.nlm.nih.gov/pubmed/22199615 http://dx.doi.org/10.1107/S1600536811050185 |
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