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Tetra­kis(μ(2)-ferrocene­carboxyl­ato-κ(2) O:O′)bis­[(methanol-κO)copper(II)] methanol disolvate

The complex mol­ecule of the title compound, [Cu(2)Fe(4)(C(5)H(5))(4)(C(6)H(4)O(2))(4)(CH(3)OH)(2)]·2CH(3)OH, lies about an inversion centre and contains two centrosymetrically related Cu(II) atoms bridged by four O:O′-bidentante ferrocene­carboxyl­ate anions, leading to a dimeric tetra­bridged unit...

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Autores principales: Artetxe, Beñat, Vitoria, Pablo, Pache, Aroa, Reinoso, Santiago, Gutiérrez-Zorrilla, Juan M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238738/
https://www.ncbi.nlm.nih.gov/pubmed/22199615
http://dx.doi.org/10.1107/S1600536811050185
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author Artetxe, Beñat
Vitoria, Pablo
Pache, Aroa
Reinoso, Santiago
Gutiérrez-Zorrilla, Juan M.
author_facet Artetxe, Beñat
Vitoria, Pablo
Pache, Aroa
Reinoso, Santiago
Gutiérrez-Zorrilla, Juan M.
author_sort Artetxe, Beñat
collection PubMed
description The complex mol­ecule of the title compound, [Cu(2)Fe(4)(C(5)H(5))(4)(C(6)H(4)O(2))(4)(CH(3)OH)(2)]·2CH(3)OH, lies about an inversion centre and contains two centrosymetrically related Cu(II) atoms bridged by four O:O′-bidentante ferrocene­carboxyl­ate anions, leading to a dimeric tetra­bridged unit with a paddle-wheel geometry. The Cu(II) atom has a distorted square-pyramidal coordination environment with four O atoms from four ferrocene­carboxyl­ate ligands in basal positions and an O atom from a methanol mol­ecule in an apical position. One of the two crystallographically independent ferrocenyl groups has a staggered conformation, while the other is eclipsed. The mol­ecules are connected into a chain along the b axis by O—H⋯O hydrogen bonds involving coordinated and uncoordinated methanol mol­ecules and the O atom from a ferrocene­carboxyl­ate unit.
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spelling pubmed-32387382011-12-23 Tetra­kis(μ(2)-ferrocene­carboxyl­ato-κ(2) O:O′)bis­[(methanol-κO)copper(II)] methanol disolvate Artetxe, Beñat Vitoria, Pablo Pache, Aroa Reinoso, Santiago Gutiérrez-Zorrilla, Juan M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complex mol­ecule of the title compound, [Cu(2)Fe(4)(C(5)H(5))(4)(C(6)H(4)O(2))(4)(CH(3)OH)(2)]·2CH(3)OH, lies about an inversion centre and contains two centrosymetrically related Cu(II) atoms bridged by four O:O′-bidentante ferrocene­carboxyl­ate anions, leading to a dimeric tetra­bridged unit with a paddle-wheel geometry. The Cu(II) atom has a distorted square-pyramidal coordination environment with four O atoms from four ferrocene­carboxyl­ate ligands in basal positions and an O atom from a methanol mol­ecule in an apical position. One of the two crystallographically independent ferrocenyl groups has a staggered conformation, while the other is eclipsed. The mol­ecules are connected into a chain along the b axis by O—H⋯O hydrogen bonds involving coordinated and uncoordinated methanol mol­ecules and the O atom from a ferrocene­carboxyl­ate unit. International Union of Crystallography 2011-11-25 /pmc/articles/PMC3238738/ /pubmed/22199615 http://dx.doi.org/10.1107/S1600536811050185 Text en © Artetxe et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Artetxe, Beñat
Vitoria, Pablo
Pache, Aroa
Reinoso, Santiago
Gutiérrez-Zorrilla, Juan M.
Tetra­kis(μ(2)-ferrocene­carboxyl­ato-κ(2) O:O′)bis­[(methanol-κO)copper(II)] methanol disolvate
title Tetra­kis(μ(2)-ferrocene­carboxyl­ato-κ(2) O:O′)bis­[(methanol-κO)copper(II)] methanol disolvate
title_full Tetra­kis(μ(2)-ferrocene­carboxyl­ato-κ(2) O:O′)bis­[(methanol-κO)copper(II)] methanol disolvate
title_fullStr Tetra­kis(μ(2)-ferrocene­carboxyl­ato-κ(2) O:O′)bis­[(methanol-κO)copper(II)] methanol disolvate
title_full_unstemmed Tetra­kis(μ(2)-ferrocene­carboxyl­ato-κ(2) O:O′)bis­[(methanol-κO)copper(II)] methanol disolvate
title_short Tetra­kis(μ(2)-ferrocene­carboxyl­ato-κ(2) O:O′)bis­[(methanol-κO)copper(II)] methanol disolvate
title_sort tetra­kis(μ(2)-ferrocene­carboxyl­ato-κ(2) o:o′)bis­[(methanol-κo)copper(ii)] methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238738/
https://www.ncbi.nlm.nih.gov/pubmed/22199615
http://dx.doi.org/10.1107/S1600536811050185
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