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[2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)­diethanol-κ(3) N,N′,O]dichloridocopper(II)

In the title complex, [CuCl(2)(C(24)H(24)N(2)O(2))], the Cu(II) cation is N,N′,O-chelated by a 2,2′-(1,1′-binaphthyl-2,2′-diyldiimino)­diethanol ligand and coordinated by two chloride anions in a distorted square-pyramidal geometry. In the diethanol ligand, the two naphthalene ring systems are twist...

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Detalles Bibliográficos
Autores principales: Huang, Wan-Yun, Liu, Dong-Cheng, Wei, Han-Chang, Liang, Fu-Pei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238740/
https://www.ncbi.nlm.nih.gov/pubmed/22199617
http://dx.doi.org/10.1107/S1600536811049828
Descripción
Sumario:In the title complex, [CuCl(2)(C(24)H(24)N(2)O(2))], the Cu(II) cation is N,N′,O-chelated by a 2,2′-(1,1′-binaphthyl-2,2′-diyldiimino)­diethanol ligand and coordinated by two chloride anions in a distorted square-pyramidal geometry. In the diethanol ligand, the two naphthalene ring systems are twisted with respect to each other at a dihedral angle of 68.30 (9)°. The uncoord­inated hy­droxy group links with a coordinated chloride anion via an intra­molecular O—H⋯Cl hydrogen bond. Inter­molecular N—H⋯O and N—H⋯Cl hydrogen bonds occur in the crystal structure.