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[2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ(3) N,N′,O]dichloridocopper(II)
In the title complex, [CuCl(2)(C(24)H(24)N(2)O(2))], the Cu(II) cation is N,N′,O-chelated by a 2,2′-(1,1′-binaphthyl-2,2′-diyldiimino)diethanol ligand and coordinated by two chloride anions in a distorted square-pyramidal geometry. In the diethanol ligand, the two naphthalene ring systems are twist...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238740/ https://www.ncbi.nlm.nih.gov/pubmed/22199617 http://dx.doi.org/10.1107/S1600536811049828 |
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author | Huang, Wan-Yun Liu, Dong-Cheng Wei, Han-Chang Liang, Fu-Pei |
author_facet | Huang, Wan-Yun Liu, Dong-Cheng Wei, Han-Chang Liang, Fu-Pei |
author_sort | Huang, Wan-Yun |
collection | PubMed |
description | In the title complex, [CuCl(2)(C(24)H(24)N(2)O(2))], the Cu(II) cation is N,N′,O-chelated by a 2,2′-(1,1′-binaphthyl-2,2′-diyldiimino)diethanol ligand and coordinated by two chloride anions in a distorted square-pyramidal geometry. In the diethanol ligand, the two naphthalene ring systems are twisted with respect to each other at a dihedral angle of 68.30 (9)°. The uncoordinated hydroxy group links with a coordinated chloride anion via an intramolecular O—H⋯Cl hydrogen bond. Intermolecular N—H⋯O and N—H⋯Cl hydrogen bonds occur in the crystal structure. |
format | Online Article Text |
id | pubmed-3238740 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32387402011-12-23 [2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ(3) N,N′,O]dichloridocopper(II) Huang, Wan-Yun Liu, Dong-Cheng Wei, Han-Chang Liang, Fu-Pei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuCl(2)(C(24)H(24)N(2)O(2))], the Cu(II) cation is N,N′,O-chelated by a 2,2′-(1,1′-binaphthyl-2,2′-diyldiimino)diethanol ligand and coordinated by two chloride anions in a distorted square-pyramidal geometry. In the diethanol ligand, the two naphthalene ring systems are twisted with respect to each other at a dihedral angle of 68.30 (9)°. The uncoordinated hydroxy group links with a coordinated chloride anion via an intramolecular O—H⋯Cl hydrogen bond. Intermolecular N—H⋯O and N—H⋯Cl hydrogen bonds occur in the crystal structure. International Union of Crystallography 2011-11-25 /pmc/articles/PMC3238740/ /pubmed/22199617 http://dx.doi.org/10.1107/S1600536811049828 Text en © Huang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Huang, Wan-Yun Liu, Dong-Cheng Wei, Han-Chang Liang, Fu-Pei [2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ(3) N,N′,O]dichloridocopper(II) |
title | [2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ(3)
N,N′,O]dichloridocopper(II) |
title_full | [2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ(3)
N,N′,O]dichloridocopper(II) |
title_fullStr | [2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ(3)
N,N′,O]dichloridocopper(II) |
title_full_unstemmed | [2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ(3)
N,N′,O]dichloridocopper(II) |
title_short | [2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ(3)
N,N′,O]dichloridocopper(II) |
title_sort | [2,2′-(1,1′-binaphthyl-2,2′-diyldiimino)diethanol-κ(3)
n,n′,o]dichloridocopper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238740/ https://www.ncbi.nlm.nih.gov/pubmed/22199617 http://dx.doi.org/10.1107/S1600536811049828 |
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