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[2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)­diethanol-κ(3) N,N′,O]dichloridocopper(II)

In the title complex, [CuCl(2)(C(24)H(24)N(2)O(2))], the Cu(II) cation is N,N′,O-chelated by a 2,2′-(1,1′-binaphthyl-2,2′-diyldiimino)­diethanol ligand and coordinated by two chloride anions in a distorted square-pyramidal geometry. In the diethanol ligand, the two naphthalene ring systems are twist...

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Autores principales: Huang, Wan-Yun, Liu, Dong-Cheng, Wei, Han-Chang, Liang, Fu-Pei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238740/
https://www.ncbi.nlm.nih.gov/pubmed/22199617
http://dx.doi.org/10.1107/S1600536811049828
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author Huang, Wan-Yun
Liu, Dong-Cheng
Wei, Han-Chang
Liang, Fu-Pei
author_facet Huang, Wan-Yun
Liu, Dong-Cheng
Wei, Han-Chang
Liang, Fu-Pei
author_sort Huang, Wan-Yun
collection PubMed
description In the title complex, [CuCl(2)(C(24)H(24)N(2)O(2))], the Cu(II) cation is N,N′,O-chelated by a 2,2′-(1,1′-binaphthyl-2,2′-diyldiimino)­diethanol ligand and coordinated by two chloride anions in a distorted square-pyramidal geometry. In the diethanol ligand, the two naphthalene ring systems are twisted with respect to each other at a dihedral angle of 68.30 (9)°. The uncoord­inated hy­droxy group links with a coordinated chloride anion via an intra­molecular O—H⋯Cl hydrogen bond. Inter­molecular N—H⋯O and N—H⋯Cl hydrogen bonds occur in the crystal structure.
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spelling pubmed-32387402011-12-23 [2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)­diethanol-κ(3) N,N′,O]dichloridocopper(II) Huang, Wan-Yun Liu, Dong-Cheng Wei, Han-Chang Liang, Fu-Pei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuCl(2)(C(24)H(24)N(2)O(2))], the Cu(II) cation is N,N′,O-chelated by a 2,2′-(1,1′-binaphthyl-2,2′-diyldiimino)­diethanol ligand and coordinated by two chloride anions in a distorted square-pyramidal geometry. In the diethanol ligand, the two naphthalene ring systems are twisted with respect to each other at a dihedral angle of 68.30 (9)°. The uncoord­inated hy­droxy group links with a coordinated chloride anion via an intra­molecular O—H⋯Cl hydrogen bond. Inter­molecular N—H⋯O and N—H⋯Cl hydrogen bonds occur in the crystal structure. International Union of Crystallography 2011-11-25 /pmc/articles/PMC3238740/ /pubmed/22199617 http://dx.doi.org/10.1107/S1600536811049828 Text en © Huang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Wan-Yun
Liu, Dong-Cheng
Wei, Han-Chang
Liang, Fu-Pei
[2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)­diethanol-κ(3) N,N′,O]dichloridocopper(II)
title [2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)­diethanol-κ(3) N,N′,O]dichloridocopper(II)
title_full [2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)­diethanol-κ(3) N,N′,O]dichloridocopper(II)
title_fullStr [2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)­diethanol-κ(3) N,N′,O]dichloridocopper(II)
title_full_unstemmed [2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)­diethanol-κ(3) N,N′,O]dichloridocopper(II)
title_short [2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)­diethanol-κ(3) N,N′,O]dichloridocopper(II)
title_sort [2,2′-(1,1′-binaphthyl-2,2′-diyldiimino)­diethanol-κ(3) n,n′,o]dichloridocopper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238740/
https://www.ncbi.nlm.nih.gov/pubmed/22199617
http://dx.doi.org/10.1107/S1600536811049828
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