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Dibromidobis{1-[4-(pyridin-4-yl)phen­yl]ethanone-κN}mercury(II)

In the title compound, [HgBr(2)(C(13)H(11)NO)(2)], the Hg(II) atom adopts a four-coordinated HgN(2)Br(2) geometry, formed by two pyridine N atoms from two ligands and two bromide anions. The complex is located on a twofold axis. The coordination geometry is close to forming a see-saw (SS-4) polyhedr...

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Detalles Bibliográficos
Autores principales: Zhang, Wen-Shen, Liu, Zhi-Juan, Xu, Feng, Xun, Qi-Ning
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238744/
https://www.ncbi.nlm.nih.gov/pubmed/22199621
http://dx.doi.org/10.1107/S1600536811049993
Descripción
Sumario:In the title compound, [HgBr(2)(C(13)H(11)NO)(2)], the Hg(II) atom adopts a four-coordinated HgN(2)Br(2) geometry, formed by two pyridine N atoms from two ligands and two bromide anions. The complex is located on a twofold axis. The coordination geometry is close to forming a see-saw (SS-4) polyhedron, the symmetry-related organic ligands being almost perpendicular; the dihedral angles between the two pyridine rings and between the two benzene rings are 85.5 (4) and 87.7 (4)°, respectively. Within the organic ligand, the pyridine ring is nearly coplanar with the benzene ring [dihedral angle = 13.1 (8)°]. In the crystal, the mol­ecular complexes are connected through weak inter­molecular C—H⋯Br contacts.