Dichlorido{N′-[(pyridin-2-yl)methyl­idene-κN]acetohydrazide-κ(2) N′,O}copper(II)

In the title compound, [CuCl(2)(C(8)H(9)N(3)O)], the Cu(II) atom has a distorted square-pyramidal CuCl(2)N(2)O coordination geometry. The tridentate acetohydrazide ligand occupies three basal positions, the fourth basal position being defined by a chloride anion at a distance of 2.2116 (6) Å. The se...

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Detalles Bibliográficos
Autores principales: Datta, Amitabha, Sheu, Shiann-Cherng, Liu, Pei-Hsin, Huang, Jui-Hsien
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238746/
https://www.ncbi.nlm.nih.gov/pubmed/22199623
http://dx.doi.org/10.1107/S1600536811049671
Descripción
Sumario:In the title compound, [CuCl(2)(C(8)H(9)N(3)O)], the Cu(II) atom has a distorted square-pyramidal CuCl(2)N(2)O coordination geometry. The tridentate acetohydrazide ligand occupies three basal positions, the fourth basal position being defined by a chloride anion at a distance of 2.2116 (6) Å. The second chloride anion is in the apical position and forms a longer Cu—Cl distance of 2.4655 (7) Å. Inter­molecular N—H⋯Cl hydrogen bonds are present in the crystal, leading to the formation of chains along [10[Image: see text]].

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