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Dichlorido{N′-[(pyridin-2-yl)methylidene-κN]acetohydrazide-κ(2) N′,O}copper(II)
In the title compound, [CuCl(2)(C(8)H(9)N(3)O)], the Cu(II) atom has a distorted square-pyramidal CuCl(2)N(2)O coordination geometry. The tridentate acetohydrazide ligand occupies three basal positions, the fourth basal position being defined by a chloride anion at a distance of 2.2116 (6) Å. The se...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238746/ https://www.ncbi.nlm.nih.gov/pubmed/22199623 http://dx.doi.org/10.1107/S1600536811049671 |
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| author | Datta, Amitabha Sheu, Shiann-Cherng Liu, Pei-Hsin Huang, Jui-Hsien |
| author_facet | Datta, Amitabha Sheu, Shiann-Cherng Liu, Pei-Hsin Huang, Jui-Hsien |
| author_sort | Datta, Amitabha |
| collection | PubMed |
| description | In the title compound, [CuCl(2)(C(8)H(9)N(3)O)], the Cu(II) atom has a distorted square-pyramidal CuCl(2)N(2)O coordination geometry. The tridentate acetohydrazide ligand occupies three basal positions, the fourth basal position being defined by a chloride anion at a distance of 2.2116 (6) Å. The second chloride anion is in the apical position and forms a longer Cu—Cl distance of 2.4655 (7) Å. Intermolecular N—H⋯Cl hydrogen bonds are present in the crystal, leading to the formation of chains along [10[Image: see text]]. |
| format | Online Article Text |
| id | pubmed-3238746 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32387462011-12-23 Dichlorido{N′-[(pyridin-2-yl)methylidene-κN]acetohydrazide-κ(2) N′,O}copper(II) Datta, Amitabha Sheu, Shiann-Cherng Liu, Pei-Hsin Huang, Jui-Hsien Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CuCl(2)(C(8)H(9)N(3)O)], the Cu(II) atom has a distorted square-pyramidal CuCl(2)N(2)O coordination geometry. The tridentate acetohydrazide ligand occupies three basal positions, the fourth basal position being defined by a chloride anion at a distance of 2.2116 (6) Å. The second chloride anion is in the apical position and forms a longer Cu—Cl distance of 2.4655 (7) Å. Intermolecular N—H⋯Cl hydrogen bonds are present in the crystal, leading to the formation of chains along [10[Image: see text]]. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238746/ /pubmed/22199623 http://dx.doi.org/10.1107/S1600536811049671 Text en © Datta et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Datta, Amitabha Sheu, Shiann-Cherng Liu, Pei-Hsin Huang, Jui-Hsien Dichlorido{N′-[(pyridin-2-yl)methylidene-κN]acetohydrazide-κ(2) N′,O}copper(II) |
| title | Dichlorido{N′-[(pyridin-2-yl)methylidene-κN]acetohydrazide-κ(2)
N′,O}copper(II) |
| title_full | Dichlorido{N′-[(pyridin-2-yl)methylidene-κN]acetohydrazide-κ(2)
N′,O}copper(II) |
| title_fullStr | Dichlorido{N′-[(pyridin-2-yl)methylidene-κN]acetohydrazide-κ(2)
N′,O}copper(II) |
| title_full_unstemmed | Dichlorido{N′-[(pyridin-2-yl)methylidene-κN]acetohydrazide-κ(2)
N′,O}copper(II) |
| title_short | Dichlorido{N′-[(pyridin-2-yl)methylidene-κN]acetohydrazide-κ(2)
N′,O}copper(II) |
| title_sort | dichlorido{n′-[(pyridin-2-yl)methylidene-κn]acetohydrazide-κ(2)
n′,o}copper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238746/ https://www.ncbi.nlm.nih.gov/pubmed/22199623 http://dx.doi.org/10.1107/S1600536811049671 |
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