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Aqua­(4-fluoro­benzoato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II) 4-fluoro­benzoate trihydrate

In the title compound, [Mn(C(7)H(4)FO(2))(C(12)H(8)N(2))(2)(H(2)O)](C(7)H(4)FO(2))·3H(2)O, the Mn(II) atom is coordinated by four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from one monodentate 4-fluoro­benzoate ion and one water mol­ecule, forming a distorted octa­hedral...

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Detalles Bibliográficos
Autores principales: Li, Yun-Xia, Zhang, Bi-Song, Wu, Chang-Sheng, Zheng, Miao, Lin, Jian-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238747/
https://www.ncbi.nlm.nih.gov/pubmed/22199624
http://dx.doi.org/10.1107/S1600536811049968
Descripción
Sumario:In the title compound, [Mn(C(7)H(4)FO(2))(C(12)H(8)N(2))(2)(H(2)O)](C(7)H(4)FO(2))·3H(2)O, the Mn(II) atom is coordinated by four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from one monodentate 4-fluoro­benzoate ion and one water mol­ecule, forming a distorted octa­hedral geometry. In the crystal, the three components are assembled into a tape structure along the a axis by O—H⋯O and C—H⋯O hydrogen bonds. Between the tapes, a π–π inter­action with a centroid–centroid distance of 3.569 (3) Å and a weak C—H⋯F hydrogen bond are observed.