Aqua­(4-fluoro­benzoato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II) 4-fluoro­benzoate trihydrate

In the title compound, [Mn(C(7)H(4)FO(2))(C(12)H(8)N(2))(2)(H(2)O)](C(7)H(4)FO(2))·3H(2)O, the Mn(II) atom is coordinated by four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from one monodentate 4-fluoro­benzoate ion and one water mol­ecule, forming a distorted octa­hedral...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Yun-Xia, Zhang, Bi-Song, Wu, Chang-Sheng, Zheng, Miao, Lin, Jian-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238747/
https://www.ncbi.nlm.nih.gov/pubmed/22199624
http://dx.doi.org/10.1107/S1600536811049968
_version_ 1782219049402368000
author Li, Yun-Xia
Zhang, Bi-Song
Wu, Chang-Sheng
Zheng, Miao
Lin, Jian-Li
author_facet Li, Yun-Xia
Zhang, Bi-Song
Wu, Chang-Sheng
Zheng, Miao
Lin, Jian-Li
author_sort Li, Yun-Xia
collection PubMed
description In the title compound, [Mn(C(7)H(4)FO(2))(C(12)H(8)N(2))(2)(H(2)O)](C(7)H(4)FO(2))·3H(2)O, the Mn(II) atom is coordinated by four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from one monodentate 4-fluoro­benzoate ion and one water mol­ecule, forming a distorted octa­hedral geometry. In the crystal, the three components are assembled into a tape structure along the a axis by O—H⋯O and C—H⋯O hydrogen bonds. Between the tapes, a π–π inter­action with a centroid–centroid distance of 3.569 (3) Å and a weak C—H⋯F hydrogen bond are observed.
format Online
Article
Text
id pubmed-3238747
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32387472011-12-23 Aqua­(4-fluoro­benzoato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II) 4-fluoro­benzoate trihydrate Li, Yun-Xia Zhang, Bi-Song Wu, Chang-Sheng Zheng, Miao Lin, Jian-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(7)H(4)FO(2))(C(12)H(8)N(2))(2)(H(2)O)](C(7)H(4)FO(2))·3H(2)O, the Mn(II) atom is coordinated by four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from one monodentate 4-fluoro­benzoate ion and one water mol­ecule, forming a distorted octa­hedral geometry. In the crystal, the three components are assembled into a tape structure along the a axis by O—H⋯O and C—H⋯O hydrogen bonds. Between the tapes, a π–π inter­action with a centroid–centroid distance of 3.569 (3) Å and a weak C—H⋯F hydrogen bond are observed. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238747/ /pubmed/22199624 http://dx.doi.org/10.1107/S1600536811049968 Text en © Li et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Yun-Xia
Zhang, Bi-Song
Wu, Chang-Sheng
Zheng, Miao
Lin, Jian-Li
Aqua­(4-fluoro­benzoato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II) 4-fluoro­benzoate trihydrate
title Aqua­(4-fluoro­benzoato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II) 4-fluoro­benzoate trihydrate
title_full Aqua­(4-fluoro­benzoato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II) 4-fluoro­benzoate trihydrate
title_fullStr Aqua­(4-fluoro­benzoato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II) 4-fluoro­benzoate trihydrate
title_full_unstemmed Aqua­(4-fluoro­benzoato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II) 4-fluoro­benzoate trihydrate
title_short Aqua­(4-fluoro­benzoato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II) 4-fluoro­benzoate trihydrate
title_sort aqua­(4-fluoro­benzoato-κo)bis­(1,10-phenanthroline-κ(2) n,n′)manganese(ii) 4-fluoro­benzoate trihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238747/
https://www.ncbi.nlm.nih.gov/pubmed/22199624
http://dx.doi.org/10.1107/S1600536811049968
work_keys_str_mv AT liyunxia aqua4fluorobenzoatokobis110phenanthrolinek2nnmanganeseii4fluorobenzoatetrihydrate
AT zhangbisong aqua4fluorobenzoatokobis110phenanthrolinek2nnmanganeseii4fluorobenzoatetrihydrate
AT wuchangsheng aqua4fluorobenzoatokobis110phenanthrolinek2nnmanganeseii4fluorobenzoatetrihydrate
AT zhengmiao aqua4fluorobenzoatokobis110phenanthrolinek2nnmanganeseii4fluorobenzoatetrihydrate
AT linjianli aqua4fluorobenzoatokobis110phenanthrolinek2nnmanganeseii4fluorobenzoatetrihydrate

Ejemplares similares