[1,5-Bis(4-fluoro­phen­yl)thio­carbazo­nato-κ(2) N (5),S]phenyl­mercury(II) dichloro­methane hemisolvate

In the title compound, [Hg(C(6)H(5))(C(13)H(9)F(2)N(4)S)]·0.5CH(2)Cl(2), the Hg(C(6)H(5)) units are twisted out of the planes of the thio­carbazo­nate ligands by 61.49 (10) and 67.79 (11)° in the two complex mol­ecules comprising the asymmetric unit. Important geometrical parameters include Hg—C = 2...

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Detalles Bibliográficos
Autores principales: von Eschwege, Karel G., Muller, Fabian, Muller, Alfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238751/
https://www.ncbi.nlm.nih.gov/pubmed/22199628
http://dx.doi.org/10.1107/S1600536811050331
Descripción
Sumario:In the title compound, [Hg(C(6)H(5))(C(13)H(9)F(2)N(4)S)]·0.5CH(2)Cl(2), the Hg(C(6)H(5)) units are twisted out of the planes of the thio­carbazo­nate ligands by 61.49 (10) and 67.79 (11)° in the two complex mol­ecules comprising the asymmetric unit. Important geometrical parameters include Hg—C = 2.079 (4) and 2.087 (4) Å, Hg—S = 2.3869 (10) and 2.3889 (11) Å, and C—Hg—S = 166.42 (12) and 168.09 (13)°. Weak intramolecular Hg—N bonding inter­actions of 2.589 (4) and 2.626 (4) Å are observed. In the crystal, C—H⋯Cl, C—H⋯F, C—H⋯N, C—H⋯π and π–π [centroid–centroid distances = 3.648 (3) and 3.641 (3) Å] inter­actions, create parallel planes along [101].

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