[1,5-Bis(4-fluoro­phen­yl)thio­carbazo­nato-κ(2) N (5),S]phenyl­mercury(II) dichloro­methane hemisolvate

In the title compound, [Hg(C(6)H(5))(C(13)H(9)F(2)N(4)S)]·0.5CH(2)Cl(2), the Hg(C(6)H(5)) units are twisted out of the planes of the thio­carbazo­nate ligands by 61.49 (10) and 67.79 (11)° in the two complex mol­ecules comprising the asymmetric unit. Important geometrical parameters include Hg—C = 2...

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Autores principales: von Eschwege, Karel G., Muller, Fabian, Muller, Alfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238751/
https://www.ncbi.nlm.nih.gov/pubmed/22199628
http://dx.doi.org/10.1107/S1600536811050331
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author von Eschwege, Karel G.
Muller, Fabian
Muller, Alfred
author_facet von Eschwege, Karel G.
Muller, Fabian
Muller, Alfred
author_sort von Eschwege, Karel G.
collection PubMed
description In the title compound, [Hg(C(6)H(5))(C(13)H(9)F(2)N(4)S)]·0.5CH(2)Cl(2), the Hg(C(6)H(5)) units are twisted out of the planes of the thio­carbazo­nate ligands by 61.49 (10) and 67.79 (11)° in the two complex mol­ecules comprising the asymmetric unit. Important geometrical parameters include Hg—C = 2.079 (4) and 2.087 (4) Å, Hg—S = 2.3869 (10) and 2.3889 (11) Å, and C—Hg—S = 166.42 (12) and 168.09 (13)°. Weak intramolecular Hg—N bonding inter­actions of 2.589 (4) and 2.626 (4) Å are observed. In the crystal, C—H⋯Cl, C—H⋯F, C—H⋯N, C—H⋯π and π–π [centroid–centroid distances = 3.648 (3) and 3.641 (3) Å] inter­actions, create parallel planes along [101].
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spelling pubmed-32387512011-12-23 [1,5-Bis(4-fluoro­phen­yl)thio­carbazo­nato-κ(2) N (5),S]phenyl­mercury(II) dichloro­methane hemisolvate von Eschwege, Karel G. Muller, Fabian Muller, Alfred Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Hg(C(6)H(5))(C(13)H(9)F(2)N(4)S)]·0.5CH(2)Cl(2), the Hg(C(6)H(5)) units are twisted out of the planes of the thio­carbazo­nate ligands by 61.49 (10) and 67.79 (11)° in the two complex mol­ecules comprising the asymmetric unit. Important geometrical parameters include Hg—C = 2.079 (4) and 2.087 (4) Å, Hg—S = 2.3869 (10) and 2.3889 (11) Å, and C—Hg—S = 166.42 (12) and 168.09 (13)°. Weak intramolecular Hg—N bonding inter­actions of 2.589 (4) and 2.626 (4) Å are observed. In the crystal, C—H⋯Cl, C—H⋯F, C—H⋯N, C—H⋯π and π–π [centroid–centroid distances = 3.648 (3) and 3.641 (3) Å] inter­actions, create parallel planes along [101]. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238751/ /pubmed/22199628 http://dx.doi.org/10.1107/S1600536811050331 Text en © Eschwege et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
von Eschwege, Karel G.
Muller, Fabian
Muller, Alfred
[1,5-Bis(4-fluoro­phen­yl)thio­carbazo­nato-κ(2) N (5),S]phenyl­mercury(II) dichloro­methane hemisolvate
title [1,5-Bis(4-fluoro­phen­yl)thio­carbazo­nato-κ(2) N (5),S]phenyl­mercury(II) dichloro­methane hemisolvate
title_full [1,5-Bis(4-fluoro­phen­yl)thio­carbazo­nato-κ(2) N (5),S]phenyl­mercury(II) dichloro­methane hemisolvate
title_fullStr [1,5-Bis(4-fluoro­phen­yl)thio­carbazo­nato-κ(2) N (5),S]phenyl­mercury(II) dichloro­methane hemisolvate
title_full_unstemmed [1,5-Bis(4-fluoro­phen­yl)thio­carbazo­nato-κ(2) N (5),S]phenyl­mercury(II) dichloro­methane hemisolvate
title_short [1,5-Bis(4-fluoro­phen­yl)thio­carbazo­nato-κ(2) N (5),S]phenyl­mercury(II) dichloro­methane hemisolvate
title_sort [1,5-bis(4-fluoro­phen­yl)thio­carbazo­nato-κ(2) n (5),s]phenyl­mercury(ii) dichloro­methane hemisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238751/
https://www.ncbi.nlm.nih.gov/pubmed/22199628
http://dx.doi.org/10.1107/S1600536811050331
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AT mulleralfred 15bis4fluorophenylthiocarbazonatok2n5sphenylmercuryiidichloromethanehemisolvate

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