[(1,2,5,6-η)-Cyclo­octa-1,5-diene]bis­(1-isopropyl-3-methyl­imidazolin-2-yl­idene)rhodium(I) tetra­fluorido­borate

In the title compound, [Rh(C(8)H(12))(C(7)H(12)N(2))(2)]BF(4), the square-planar Rh complex cation and the BF(4) (−) anion are both bis­ected by a crystallographic twofold rotation axis. The Rh and B atoms lie on this axis and all others are in general positions. In the crystal, two unique C—H⋯F hyd...

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Detalles Bibliográficos
Autores principales: Nichol, Gary S., Rajaseelan, Jonathan, Walton, David P., Rajaseelan, Edward
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238752/
https://www.ncbi.nlm.nih.gov/pubmed/22199629
http://dx.doi.org/10.1107/S1600536811049890
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author Nichol, Gary S.
Rajaseelan, Jonathan
Walton, David P.
Rajaseelan, Edward
author_facet Nichol, Gary S.
Rajaseelan, Jonathan
Walton, David P.
Rajaseelan, Edward
author_sort Nichol, Gary S.
collection PubMed
description In the title compound, [Rh(C(8)H(12))(C(7)H(12)N(2))(2)]BF(4), the square-planar Rh complex cation and the BF(4) (−) anion are both bis­ected by a crystallographic twofold rotation axis. The Rh and B atoms lie on this axis and all others are in general positions. In the crystal, two unique C—H⋯F hydrogen-bonding inter­actions are present, which involve both imidazolin-2-yl­idene H atoms. They form two separate C(5) motifs, the combination of which is a rippled hydrogen-bonded sheet structure in the ab plane.
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spelling pubmed-32387522011-12-23 [(1,2,5,6-η)-Cyclo­octa-1,5-diene]bis­(1-isopropyl-3-methyl­imidazolin-2-yl­idene)rhodium(I) tetra­fluorido­borate Nichol, Gary S. Rajaseelan, Jonathan Walton, David P. Rajaseelan, Edward Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Rh(C(8)H(12))(C(7)H(12)N(2))(2)]BF(4), the square-planar Rh complex cation and the BF(4) (−) anion are both bis­ected by a crystallographic twofold rotation axis. The Rh and B atoms lie on this axis and all others are in general positions. In the crystal, two unique C—H⋯F hydrogen-bonding inter­actions are present, which involve both imidazolin-2-yl­idene H atoms. They form two separate C(5) motifs, the combination of which is a rippled hydrogen-bonded sheet structure in the ab plane. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238752/ /pubmed/22199629 http://dx.doi.org/10.1107/S1600536811049890 Text en © Nichol et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nichol, Gary S.
Rajaseelan, Jonathan
Walton, David P.
Rajaseelan, Edward
[(1,2,5,6-η)-Cyclo­octa-1,5-diene]bis­(1-isopropyl-3-methyl­imidazolin-2-yl­idene)rhodium(I) tetra­fluorido­borate
title [(1,2,5,6-η)-Cyclo­octa-1,5-diene]bis­(1-isopropyl-3-methyl­imidazolin-2-yl­idene)rhodium(I) tetra­fluorido­borate
title_full [(1,2,5,6-η)-Cyclo­octa-1,5-diene]bis­(1-isopropyl-3-methyl­imidazolin-2-yl­idene)rhodium(I) tetra­fluorido­borate
title_fullStr [(1,2,5,6-η)-Cyclo­octa-1,5-diene]bis­(1-isopropyl-3-methyl­imidazolin-2-yl­idene)rhodium(I) tetra­fluorido­borate
title_full_unstemmed [(1,2,5,6-η)-Cyclo­octa-1,5-diene]bis­(1-isopropyl-3-methyl­imidazolin-2-yl­idene)rhodium(I) tetra­fluorido­borate
title_short [(1,2,5,6-η)-Cyclo­octa-1,5-diene]bis­(1-isopropyl-3-methyl­imidazolin-2-yl­idene)rhodium(I) tetra­fluorido­borate
title_sort [(1,2,5,6-η)-cyclo­octa-1,5-diene]bis­(1-isopropyl-3-methyl­imidazolin-2-yl­idene)rhodium(i) tetra­fluorido­borate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238752/
https://www.ncbi.nlm.nih.gov/pubmed/22199629
http://dx.doi.org/10.1107/S1600536811049890
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