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Poly[aqua­{μ(3)-5-[(pyridin-2-ylmeth­yl)amino]­isophthalato-κ(5) N,N′:O (1),O (1′):O (3)}cobalt(II)]

In the title polymer, {[Co(C(14)H(10)N(2)O(4))(H(2)O)]·3.5H(2)O}(n), the Co(2+) ion is coordinated by three carboxyl­ate O atoms from two 5-[(pyridin-2-ylmeth­yl)amino]­isophthalate anions, two N atoms from a (pyridin-2-ylmeth­yl)amino group and an O atom from a water mol­ecule, furnishing a distort...

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Detalles Bibliográficos
Autores principales: Zhu, Xiao-Hong, Cheng, Xiao-Chun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238753/
https://www.ncbi.nlm.nih.gov/pubmed/22199630
http://dx.doi.org/10.1107/S1600536811050318
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author Zhu, Xiao-Hong
Cheng, Xiao-Chun
author_facet Zhu, Xiao-Hong
Cheng, Xiao-Chun
author_sort Zhu, Xiao-Hong
collection PubMed
description In the title polymer, {[Co(C(14)H(10)N(2)O(4))(H(2)O)]·3.5H(2)O}(n), the Co(2+) ion is coordinated by three carboxyl­ate O atoms from two 5-[(pyridin-2-ylmeth­yl)amino]­isophthalate anions, two N atoms from a (pyridin-2-ylmeth­yl)amino group and an O atom from a water mol­ecule, furnishing a distorted CoO(4)N(2) octa­hedral geometry. Each anion acts as a μ(3)-bridge, linking cobalt ions into a two-dimensional layer parallel to (100). The asymmetric unit also contains three and a half solvent water mol­ecules, which could not be modeled. Therefore, the diffraction contribution of the solvent water mol­ecules was removed by the subroutine SQUEEZE in PLATON [Spek (2009). Acta Cryst. D65, 148–155]. The crystal structure is stabilized by O—H⋯O hydrogen bonds in which the coordinated water mol­ecule acts as donor and the carboxyl­ate O atoms as acceptors.
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spelling pubmed-32387532011-12-23 Poly[aqua­{μ(3)-5-[(pyridin-2-ylmeth­yl)amino]­isophthalato-κ(5) N,N′:O (1),O (1′):O (3)}cobalt(II)] Zhu, Xiao-Hong Cheng, Xiao-Chun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymer, {[Co(C(14)H(10)N(2)O(4))(H(2)O)]·3.5H(2)O}(n), the Co(2+) ion is coordinated by three carboxyl­ate O atoms from two 5-[(pyridin-2-ylmeth­yl)amino]­isophthalate anions, two N atoms from a (pyridin-2-ylmeth­yl)amino group and an O atom from a water mol­ecule, furnishing a distorted CoO(4)N(2) octa­hedral geometry. Each anion acts as a μ(3)-bridge, linking cobalt ions into a two-dimensional layer parallel to (100). The asymmetric unit also contains three and a half solvent water mol­ecules, which could not be modeled. Therefore, the diffraction contribution of the solvent water mol­ecules was removed by the subroutine SQUEEZE in PLATON [Spek (2009). Acta Cryst. D65, 148–155]. The crystal structure is stabilized by O—H⋯O hydrogen bonds in which the coordinated water mol­ecule acts as donor and the carboxyl­ate O atoms as acceptors. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238753/ /pubmed/22199630 http://dx.doi.org/10.1107/S1600536811050318 Text en © Zhu and Cheng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Xiao-Hong
Cheng, Xiao-Chun
Poly[aqua­{μ(3)-5-[(pyridin-2-ylmeth­yl)amino]­isophthalato-κ(5) N,N′:O (1),O (1′):O (3)}cobalt(II)]
title Poly[aqua­{μ(3)-5-[(pyridin-2-ylmeth­yl)amino]­isophthalato-κ(5) N,N′:O (1),O (1′):O (3)}cobalt(II)]
title_full Poly[aqua­{μ(3)-5-[(pyridin-2-ylmeth­yl)amino]­isophthalato-κ(5) N,N′:O (1),O (1′):O (3)}cobalt(II)]
title_fullStr Poly[aqua­{μ(3)-5-[(pyridin-2-ylmeth­yl)amino]­isophthalato-κ(5) N,N′:O (1),O (1′):O (3)}cobalt(II)]
title_full_unstemmed Poly[aqua­{μ(3)-5-[(pyridin-2-ylmeth­yl)amino]­isophthalato-κ(5) N,N′:O (1),O (1′):O (3)}cobalt(II)]
title_short Poly[aqua­{μ(3)-5-[(pyridin-2-ylmeth­yl)amino]­isophthalato-κ(5) N,N′:O (1),O (1′):O (3)}cobalt(II)]
title_sort poly[aqua­{μ(3)-5-[(pyridin-2-ylmeth­yl)amino]­isophthalato-κ(5) n,n′:o (1),o (1′):o (3)}cobalt(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238753/
https://www.ncbi.nlm.nih.gov/pubmed/22199630
http://dx.doi.org/10.1107/S1600536811050318
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