Cargando…
Poly[aqua{μ(3)-5-[(pyridin-2-ylmethyl)amino]isophthalato-κ(5) N,N′:O (1),O (1′):O (3)}cobalt(II)]
In the title polymer, {[Co(C(14)H(10)N(2)O(4))(H(2)O)]·3.5H(2)O}(n), the Co(2+) ion is coordinated by three carboxylate O atoms from two 5-[(pyridin-2-ylmethyl)amino]isophthalate anions, two N atoms from a (pyridin-2-ylmethyl)amino group and an O atom from a water molecule, furnishing a distort...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238753/ https://www.ncbi.nlm.nih.gov/pubmed/22199630 http://dx.doi.org/10.1107/S1600536811050318 |
_version_ | 1782219050764468224 |
---|---|
author | Zhu, Xiao-Hong Cheng, Xiao-Chun |
author_facet | Zhu, Xiao-Hong Cheng, Xiao-Chun |
author_sort | Zhu, Xiao-Hong |
collection | PubMed |
description | In the title polymer, {[Co(C(14)H(10)N(2)O(4))(H(2)O)]·3.5H(2)O}(n), the Co(2+) ion is coordinated by three carboxylate O atoms from two 5-[(pyridin-2-ylmethyl)amino]isophthalate anions, two N atoms from a (pyridin-2-ylmethyl)amino group and an O atom from a water molecule, furnishing a distorted CoO(4)N(2) octahedral geometry. Each anion acts as a μ(3)-bridge, linking cobalt ions into a two-dimensional layer parallel to (100). The asymmetric unit also contains three and a half solvent water molecules, which could not be modeled. Therefore, the diffraction contribution of the solvent water molecules was removed by the subroutine SQUEEZE in PLATON [Spek (2009). Acta Cryst. D65, 148–155]. The crystal structure is stabilized by O—H⋯O hydrogen bonds in which the coordinated water molecule acts as donor and the carboxylate O atoms as acceptors. |
format | Online Article Text |
id | pubmed-3238753 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32387532011-12-23 Poly[aqua{μ(3)-5-[(pyridin-2-ylmethyl)amino]isophthalato-κ(5) N,N′:O (1),O (1′):O (3)}cobalt(II)] Zhu, Xiao-Hong Cheng, Xiao-Chun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymer, {[Co(C(14)H(10)N(2)O(4))(H(2)O)]·3.5H(2)O}(n), the Co(2+) ion is coordinated by three carboxylate O atoms from two 5-[(pyridin-2-ylmethyl)amino]isophthalate anions, two N atoms from a (pyridin-2-ylmethyl)amino group and an O atom from a water molecule, furnishing a distorted CoO(4)N(2) octahedral geometry. Each anion acts as a μ(3)-bridge, linking cobalt ions into a two-dimensional layer parallel to (100). The asymmetric unit also contains three and a half solvent water molecules, which could not be modeled. Therefore, the diffraction contribution of the solvent water molecules was removed by the subroutine SQUEEZE in PLATON [Spek (2009). Acta Cryst. D65, 148–155]. The crystal structure is stabilized by O—H⋯O hydrogen bonds in which the coordinated water molecule acts as donor and the carboxylate O atoms as acceptors. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238753/ /pubmed/22199630 http://dx.doi.org/10.1107/S1600536811050318 Text en © Zhu and Cheng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhu, Xiao-Hong Cheng, Xiao-Chun Poly[aqua{μ(3)-5-[(pyridin-2-ylmethyl)amino]isophthalato-κ(5) N,N′:O (1),O (1′):O (3)}cobalt(II)] |
title | Poly[aqua{μ(3)-5-[(pyridin-2-ylmethyl)amino]isophthalato-κ(5)
N,N′:O
(1),O
(1′):O
(3)}cobalt(II)] |
title_full | Poly[aqua{μ(3)-5-[(pyridin-2-ylmethyl)amino]isophthalato-κ(5)
N,N′:O
(1),O
(1′):O
(3)}cobalt(II)] |
title_fullStr | Poly[aqua{μ(3)-5-[(pyridin-2-ylmethyl)amino]isophthalato-κ(5)
N,N′:O
(1),O
(1′):O
(3)}cobalt(II)] |
title_full_unstemmed | Poly[aqua{μ(3)-5-[(pyridin-2-ylmethyl)amino]isophthalato-κ(5)
N,N′:O
(1),O
(1′):O
(3)}cobalt(II)] |
title_short | Poly[aqua{μ(3)-5-[(pyridin-2-ylmethyl)amino]isophthalato-κ(5)
N,N′:O
(1),O
(1′):O
(3)}cobalt(II)] |
title_sort | poly[aqua{μ(3)-5-[(pyridin-2-ylmethyl)amino]isophthalato-κ(5)
n,n′:o
(1),o
(1′):o
(3)}cobalt(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238753/ https://www.ncbi.nlm.nih.gov/pubmed/22199630 http://dx.doi.org/10.1107/S1600536811050318 |
work_keys_str_mv | AT zhuxiaohong polyaquam35pyridin2ylmethylaminoisophthalatok5nno1o1o3cobaltii AT chengxiaochun polyaquam35pyridin2ylmethylaminoisophthalatok5nno1o1o3cobaltii |