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Bis{μ(2)-2-[(2-hydroxyethyl)(methyl)amino]ethanolato}bis(μ(3)-N-methyl-2,2′-azanediyldiethanolato)tetrakis(thiocyanatato-κN)dichromium(III)dimanganese(II) dimethylformamide tetrasolvate
The heterometallic title complex, [Cr(2)Mn(2)(C(5)H(11)NO(2))(2)(C(5)H(12)NO(2))(2)(NCS)(4)]·4C(3)H(7)NO, was prepared using manganese powder, Reineckes salt, ammonium thiocyanate and a non-aqueous solution of N-methyldiethanolamine in air. The centrosymmetric molecular structure of the complex...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238755/ https://www.ncbi.nlm.nih.gov/pubmed/22199632 http://dx.doi.org/10.1107/S1600536811049336 |
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| author | Semenaka, Valentyna V. Nesterova, Oksana V. Kokozay, Volodymyr N. Zubatyuk, Roman I. Shishkin, Oleg V. |
| author_facet | Semenaka, Valentyna V. Nesterova, Oksana V. Kokozay, Volodymyr N. Zubatyuk, Roman I. Shishkin, Oleg V. |
| author_sort | Semenaka, Valentyna V. |
| collection | PubMed |
| description | The heterometallic title complex, [Cr(2)Mn(2)(C(5)H(11)NO(2))(2)(C(5)H(12)NO(2))(2)(NCS)(4)]·4C(3)H(7)NO, was prepared using manganese powder, Reineckes salt, ammonium thiocyanate and a non-aqueous solution of N-methyldiethanolamine in air. The centrosymmetric molecular structure of the complex is based on a tetranuclear {Mn(2)Cr(2)(μ-O)(6)} core. The tetranuclear complex molecule and the two uncoordinated dimethylformamide molecules are linked by O—H⋯O hydrogen bonds, while the two other molecules of dimethylformamide do not participate in hydrogen bonding. |
| format | Online Article Text |
| id | pubmed-3238755 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32387552011-12-23 Bis{μ(2)-2-[(2-hydroxyethyl)(methyl)amino]ethanolato}bis(μ(3)-N-methyl-2,2′-azanediyldiethanolato)tetrakis(thiocyanatato-κN)dichromium(III)dimanganese(II) dimethylformamide tetrasolvate Semenaka, Valentyna V. Nesterova, Oksana V. Kokozay, Volodymyr N. Zubatyuk, Roman I. Shishkin, Oleg V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The heterometallic title complex, [Cr(2)Mn(2)(C(5)H(11)NO(2))(2)(C(5)H(12)NO(2))(2)(NCS)(4)]·4C(3)H(7)NO, was prepared using manganese powder, Reineckes salt, ammonium thiocyanate and a non-aqueous solution of N-methyldiethanolamine in air. The centrosymmetric molecular structure of the complex is based on a tetranuclear {Mn(2)Cr(2)(μ-O)(6)} core. The tetranuclear complex molecule and the two uncoordinated dimethylformamide molecules are linked by O—H⋯O hydrogen bonds, while the two other molecules of dimethylformamide do not participate in hydrogen bonding. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238755/ /pubmed/22199632 http://dx.doi.org/10.1107/S1600536811049336 Text en © Semenaka et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Semenaka, Valentyna V. Nesterova, Oksana V. Kokozay, Volodymyr N. Zubatyuk, Roman I. Shishkin, Oleg V. Bis{μ(2)-2-[(2-hydroxyethyl)(methyl)amino]ethanolato}bis(μ(3)-N-methyl-2,2′-azanediyldiethanolato)tetrakis(thiocyanatato-κN)dichromium(III)dimanganese(II) dimethylformamide tetrasolvate |
| title | Bis{μ(2)-2-[(2-hydroxyethyl)(methyl)amino]ethanolato}bis(μ(3)-N-methyl-2,2′-azanediyldiethanolato)tetrakis(thiocyanatato-κN)dichromium(III)dimanganese(II) dimethylformamide tetrasolvate |
| title_full | Bis{μ(2)-2-[(2-hydroxyethyl)(methyl)amino]ethanolato}bis(μ(3)-N-methyl-2,2′-azanediyldiethanolato)tetrakis(thiocyanatato-κN)dichromium(III)dimanganese(II) dimethylformamide tetrasolvate |
| title_fullStr | Bis{μ(2)-2-[(2-hydroxyethyl)(methyl)amino]ethanolato}bis(μ(3)-N-methyl-2,2′-azanediyldiethanolato)tetrakis(thiocyanatato-κN)dichromium(III)dimanganese(II) dimethylformamide tetrasolvate |
| title_full_unstemmed | Bis{μ(2)-2-[(2-hydroxyethyl)(methyl)amino]ethanolato}bis(μ(3)-N-methyl-2,2′-azanediyldiethanolato)tetrakis(thiocyanatato-κN)dichromium(III)dimanganese(II) dimethylformamide tetrasolvate |
| title_short | Bis{μ(2)-2-[(2-hydroxyethyl)(methyl)amino]ethanolato}bis(μ(3)-N-methyl-2,2′-azanediyldiethanolato)tetrakis(thiocyanatato-κN)dichromium(III)dimanganese(II) dimethylformamide tetrasolvate |
| title_sort | bis{μ(2)-2-[(2-hydroxyethyl)(methyl)amino]ethanolato}bis(μ(3)-n-methyl-2,2′-azanediyldiethanolato)tetrakis(thiocyanatato-κn)dichromium(iii)dimanganese(ii) dimethylformamide tetrasolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238755/ https://www.ncbi.nlm.nih.gov/pubmed/22199632 http://dx.doi.org/10.1107/S1600536811049336 |
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