Cargando…
Aqua(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)(nitrato-κO)(nitrato-κ(2) O,O′)zinc
In the title compound, [Zn(NO(3))(2)(C(12)H(12)N(2))(H(2)O)], the Zn(II) atom is six-coordinated in a distorted octahedral geometry by two N atoms from a chelating 4,4′-dimethyl-2,2′-bipyridine ligand, one water O atom, one O atom from a monodentate nitrate anion and two O atoms from a chelating ni...
| Autores principales: | , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238756/ https://www.ncbi.nlm.nih.gov/pubmed/22199633 http://dx.doi.org/10.1107/S1600536811050227 |
| _version_ | 1782219051446042624 |
|---|---|
| author | Shirvan, Sadif A. Haydari Dezfuli, Sara |
| author_facet | Shirvan, Sadif A. Haydari Dezfuli, Sara |
| author_sort | Shirvan, Sadif A. |
| collection | PubMed |
| description | In the title compound, [Zn(NO(3))(2)(C(12)H(12)N(2))(H(2)O)], the Zn(II) atom is six-coordinated in a distorted octahedral geometry by two N atoms from a chelating 4,4′-dimethyl-2,2′-bipyridine ligand, one water O atom, one O atom from a monodentate nitrate anion and two O atoms from a chelating nitrate anion. In the crystal, there are aromatic π–π contacts between the pyridine rings [centroid–centroid distances = 3.9577 (13) Å] and intermolecular O—H⋯O and C—H⋯O hydrogen bonds. |
| format | Online Article Text |
| id | pubmed-3238756 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32387562011-12-23 Aqua(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)(nitrato-κO)(nitrato-κ(2) O,O′)zinc Shirvan, Sadif A. Haydari Dezfuli, Sara Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(NO(3))(2)(C(12)H(12)N(2))(H(2)O)], the Zn(II) atom is six-coordinated in a distorted octahedral geometry by two N atoms from a chelating 4,4′-dimethyl-2,2′-bipyridine ligand, one water O atom, one O atom from a monodentate nitrate anion and two O atoms from a chelating nitrate anion. In the crystal, there are aromatic π–π contacts between the pyridine rings [centroid–centroid distances = 3.9577 (13) Å] and intermolecular O—H⋯O and C—H⋯O hydrogen bonds. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238756/ /pubmed/22199633 http://dx.doi.org/10.1107/S1600536811050227 Text en © Shirvan and Haydari Dezfuli 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Shirvan, Sadif A. Haydari Dezfuli, Sara Aqua(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)(nitrato-κO)(nitrato-κ(2) O,O′)zinc |
| title | Aqua(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)(nitrato-κO)(nitrato-κ(2)
O,O′)zinc |
| title_full | Aqua(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)(nitrato-κO)(nitrato-κ(2)
O,O′)zinc |
| title_fullStr | Aqua(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)(nitrato-κO)(nitrato-κ(2)
O,O′)zinc |
| title_full_unstemmed | Aqua(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)(nitrato-κO)(nitrato-κ(2)
O,O′)zinc |
| title_short | Aqua(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)(nitrato-κO)(nitrato-κ(2)
O,O′)zinc |
| title_sort | aqua(4,4′-dimethyl-2,2′-bipyridine-κ(2)
n,n′)(nitrato-κo)(nitrato-κ(2)
o,o′)zinc |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238756/ https://www.ncbi.nlm.nih.gov/pubmed/22199633 http://dx.doi.org/10.1107/S1600536811050227 |
| work_keys_str_mv | AT shirvansadifa aqua44dimethyl22bipyridinek2nnnitratokonitratok2oozinc AT haydaridezfulisara aqua44dimethyl22bipyridinek2nnnitratokonitratok2oozinc |