Bis(di-2-pyridyl­amine-κ(2) N,N′)bis­(thio­cyanato-κN)nickel(II)

The mononuclear neutral title complex, [Ni(NCS)(2)(C(10)H(9)N(3))(2)], shows a cis-octa­hedral geometry around the Ni(II) ion, formed by two chelating di-2-pyridyl­amine (Hdpa) ligands and two thio­cyanate anions. Both amine H atoms are involved in N—H⋯S hydrogen bonding, resulting in the formation...

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Detalles Bibliográficos
Autor principal: Dobrzańska, Liliana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238757/
https://www.ncbi.nlm.nih.gov/pubmed/22199634
http://dx.doi.org/10.1107/S1600536811050197
Descripción
Sumario:The mononuclear neutral title complex, [Ni(NCS)(2)(C(10)H(9)N(3))(2)], shows a cis-octa­hedral geometry around the Ni(II) ion, formed by two chelating di-2-pyridyl­amine (Hdpa) ligands and two thio­cyanate anions. Both amine H atoms are involved in N—H⋯S hydrogen bonding, resulting in the formation of layers of inter­linked mol­ecules parallel to the ab plane, which are further held together by weak π–π inter­actions between adjacent complexes, involving one ring of each dipyridyl­amine unit [centroid–centroid distance = 3.777 (4) Å], forming a three-dimensional assembly.

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