Bis(di-2-pyridyl­amine-κ(2) N,N′)bis­(thio­cyanato-κN)nickel(II)

The mononuclear neutral title complex, [Ni(NCS)(2)(C(10)H(9)N(3))(2)], shows a cis-octa­hedral geometry around the Ni(II) ion, formed by two chelating di-2-pyridyl­amine (Hdpa) ligands and two thio­cyanate anions. Both amine H atoms are involved in N—H⋯S hydrogen bonding, resulting in the formation...

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Detalles Bibliográficos
Autor principal: Dobrzańska, Liliana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238757/
https://www.ncbi.nlm.nih.gov/pubmed/22199634
http://dx.doi.org/10.1107/S1600536811050197
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author Dobrzańska, Liliana
author_facet Dobrzańska, Liliana
author_sort Dobrzańska, Liliana
collection PubMed
description The mononuclear neutral title complex, [Ni(NCS)(2)(C(10)H(9)N(3))(2)], shows a cis-octa­hedral geometry around the Ni(II) ion, formed by two chelating di-2-pyridyl­amine (Hdpa) ligands and two thio­cyanate anions. Both amine H atoms are involved in N—H⋯S hydrogen bonding, resulting in the formation of layers of inter­linked mol­ecules parallel to the ab plane, which are further held together by weak π–π inter­actions between adjacent complexes, involving one ring of each dipyridyl­amine unit [centroid–centroid distance = 3.777 (4) Å], forming a three-dimensional assembly.
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spelling pubmed-32387572011-12-23 Bis(di-2-pyridyl­amine-κ(2) N,N′)bis­(thio­cyanato-κN)nickel(II) Dobrzańska, Liliana Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mononuclear neutral title complex, [Ni(NCS)(2)(C(10)H(9)N(3))(2)], shows a cis-octa­hedral geometry around the Ni(II) ion, formed by two chelating di-2-pyridyl­amine (Hdpa) ligands and two thio­cyanate anions. Both amine H atoms are involved in N—H⋯S hydrogen bonding, resulting in the formation of layers of inter­linked mol­ecules parallel to the ab plane, which are further held together by weak π–π inter­actions between adjacent complexes, involving one ring of each dipyridyl­amine unit [centroid–centroid distance = 3.777 (4) Å], forming a three-dimensional assembly. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238757/ /pubmed/22199634 http://dx.doi.org/10.1107/S1600536811050197 Text en © Liliana Dobrzańska 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dobrzańska, Liliana
Bis(di-2-pyridyl­amine-κ(2) N,N′)bis­(thio­cyanato-κN)nickel(II)
title Bis(di-2-pyridyl­amine-κ(2) N,N′)bis­(thio­cyanato-κN)nickel(II)
title_full Bis(di-2-pyridyl­amine-κ(2) N,N′)bis­(thio­cyanato-κN)nickel(II)
title_fullStr Bis(di-2-pyridyl­amine-κ(2) N,N′)bis­(thio­cyanato-κN)nickel(II)
title_full_unstemmed Bis(di-2-pyridyl­amine-κ(2) N,N′)bis­(thio­cyanato-κN)nickel(II)
title_short Bis(di-2-pyridyl­amine-κ(2) N,N′)bis­(thio­cyanato-κN)nickel(II)
title_sort bis(di-2-pyridyl­amine-κ(2) n,n′)bis­(thio­cyanato-κn)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238757/
https://www.ncbi.nlm.nih.gov/pubmed/22199634
http://dx.doi.org/10.1107/S1600536811050197
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