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Dicyclohexylammonium trimethylbis(hydrogen phenylphosphonato)stannate(IV)
In the title compound, (C(12)H(24)N)[Sn(CH(3))(3)(C(6)H(6)O(3)P)(2)], the SnMe(3) residues are axially coordinated by two monodentate [PhPO(3)H](−) anions, leading to a trigonal–bipyramidal geometry for the Sn(IV) atom. The two [SnMe(3)(PhPO(3)H)(2)](−) anions in the unit cell are associated into in...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238759/ https://www.ncbi.nlm.nih.gov/pubmed/22199636 http://dx.doi.org/10.1107/S1600536811049567 |
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author | Diop, Tidiane Diop, Libasse Diop, Cheikh A. K. Molloy, Kieran C. Kociok-Köhn, Gabriele |
author_facet | Diop, Tidiane Diop, Libasse Diop, Cheikh A. K. Molloy, Kieran C. Kociok-Köhn, Gabriele |
author_sort | Diop, Tidiane |
collection | PubMed |
description | In the title compound, (C(12)H(24)N)[Sn(CH(3))(3)(C(6)H(6)O(3)P)(2)], the SnMe(3) residues are axially coordinated by two monodentate [PhPO(3)H](−) anions, leading to a trigonal–bipyramidal geometry for the Sn(IV) atom. The two [SnMe(3)(PhPO(3)H)(2)](−) anions in the unit cell are associated into infinite chains along the a axis by O—H⋯O hydrogen bonds involving the hydroxy group of the hydrogen phenylphosphonate ion. The chains interact with one another via O—H⋯O hydrogen bonds along the c axis. These networks of anions assemble with the dicyclohexylammonium ion through N—H⋯O hydrogen bonds, forming a three-dimensional network. |
format | Online Article Text |
id | pubmed-3238759 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32387592011-12-23 Dicyclohexylammonium trimethylbis(hydrogen phenylphosphonato)stannate(IV) Diop, Tidiane Diop, Libasse Diop, Cheikh A. K. Molloy, Kieran C. Kociok-Köhn, Gabriele Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(12)H(24)N)[Sn(CH(3))(3)(C(6)H(6)O(3)P)(2)], the SnMe(3) residues are axially coordinated by two monodentate [PhPO(3)H](−) anions, leading to a trigonal–bipyramidal geometry for the Sn(IV) atom. The two [SnMe(3)(PhPO(3)H)(2)](−) anions in the unit cell are associated into infinite chains along the a axis by O—H⋯O hydrogen bonds involving the hydroxy group of the hydrogen phenylphosphonate ion. The chains interact with one another via O—H⋯O hydrogen bonds along the c axis. These networks of anions assemble with the dicyclohexylammonium ion through N—H⋯O hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238759/ /pubmed/22199636 http://dx.doi.org/10.1107/S1600536811049567 Text en © Diop et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Diop, Tidiane Diop, Libasse Diop, Cheikh A. K. Molloy, Kieran C. Kociok-Köhn, Gabriele Dicyclohexylammonium trimethylbis(hydrogen phenylphosphonato)stannate(IV) |
title | Dicyclohexylammonium trimethylbis(hydrogen phenylphosphonato)stannate(IV) |
title_full | Dicyclohexylammonium trimethylbis(hydrogen phenylphosphonato)stannate(IV) |
title_fullStr | Dicyclohexylammonium trimethylbis(hydrogen phenylphosphonato)stannate(IV) |
title_full_unstemmed | Dicyclohexylammonium trimethylbis(hydrogen phenylphosphonato)stannate(IV) |
title_short | Dicyclohexylammonium trimethylbis(hydrogen phenylphosphonato)stannate(IV) |
title_sort | dicyclohexylammonium trimethylbis(hydrogen phenylphosphonato)stannate(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238759/ https://www.ncbi.nlm.nih.gov/pubmed/22199636 http://dx.doi.org/10.1107/S1600536811049567 |
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