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Dicyclo­hexyl­ammonium trimethyl­bis­(hydrogen phenyl­phospho­nato)stannate(IV)

In the title compound, (C(12)H(24)N)[Sn(CH(3))(3)(C(6)H(6)O(3)P)(2)], the SnMe(3) residues are axially coordinated by two monodentate [PhPO(3)H](−) anions, leading to a trigonal–bipyramidal geometry for the Sn(IV) atom. The two [SnMe(3)(PhPO(3)H)(2)](−) anions in the unit cell are associated into in...

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Autores principales: Diop, Tidiane, Diop, Libasse, Diop, Cheikh A. K., Molloy, Kieran C., Kociok-Köhn, Gabriele
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238759/
https://www.ncbi.nlm.nih.gov/pubmed/22199636
http://dx.doi.org/10.1107/S1600536811049567
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author Diop, Tidiane
Diop, Libasse
Diop, Cheikh A. K.
Molloy, Kieran C.
Kociok-Köhn, Gabriele
author_facet Diop, Tidiane
Diop, Libasse
Diop, Cheikh A. K.
Molloy, Kieran C.
Kociok-Köhn, Gabriele
author_sort Diop, Tidiane
collection PubMed
description In the title compound, (C(12)H(24)N)[Sn(CH(3))(3)(C(6)H(6)O(3)P)(2)], the SnMe(3) residues are axially coordinated by two monodentate [PhPO(3)H](−) anions, leading to a trigonal–bipyramidal geometry for the Sn(IV) atom. The two [SnMe(3)(PhPO(3)H)(2)](−) anions in the unit cell are associated into infinite chains along the a axis by O—H⋯O hydrogen bonds involving the hy­droxy group of the hydrogen phenyl­phospho­nate ion. The chains inter­act with one another via O—H⋯O hydrogen bonds along the c axis. These networks of anions assemble with the dicyclo­hexyl­ammonium ion through N—H⋯O hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-32387592011-12-23 Dicyclo­hexyl­ammonium trimethyl­bis­(hydrogen phenyl­phospho­nato)stannate(IV) Diop, Tidiane Diop, Libasse Diop, Cheikh A. K. Molloy, Kieran C. Kociok-Köhn, Gabriele Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(12)H(24)N)[Sn(CH(3))(3)(C(6)H(6)O(3)P)(2)], the SnMe(3) residues are axially coordinated by two monodentate [PhPO(3)H](−) anions, leading to a trigonal–bipyramidal geometry for the Sn(IV) atom. The two [SnMe(3)(PhPO(3)H)(2)](−) anions in the unit cell are associated into infinite chains along the a axis by O—H⋯O hydrogen bonds involving the hy­droxy group of the hydrogen phenyl­phospho­nate ion. The chains inter­act with one another via O—H⋯O hydrogen bonds along the c axis. These networks of anions assemble with the dicyclo­hexyl­ammonium ion through N—H⋯O hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238759/ /pubmed/22199636 http://dx.doi.org/10.1107/S1600536811049567 Text en © Diop et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Diop, Tidiane
Diop, Libasse
Diop, Cheikh A. K.
Molloy, Kieran C.
Kociok-Köhn, Gabriele
Dicyclo­hexyl­ammonium trimethyl­bis­(hydrogen phenyl­phospho­nato)stannate(IV)
title Dicyclo­hexyl­ammonium trimethyl­bis­(hydrogen phenyl­phospho­nato)stannate(IV)
title_full Dicyclo­hexyl­ammonium trimethyl­bis­(hydrogen phenyl­phospho­nato)stannate(IV)
title_fullStr Dicyclo­hexyl­ammonium trimethyl­bis­(hydrogen phenyl­phospho­nato)stannate(IV)
title_full_unstemmed Dicyclo­hexyl­ammonium trimethyl­bis­(hydrogen phenyl­phospho­nato)stannate(IV)
title_short Dicyclo­hexyl­ammonium trimethyl­bis­(hydrogen phenyl­phospho­nato)stannate(IV)
title_sort dicyclo­hexyl­ammonium trimethyl­bis­(hydrogen phenyl­phospho­nato)stannate(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238759/
https://www.ncbi.nlm.nih.gov/pubmed/22199636
http://dx.doi.org/10.1107/S1600536811049567
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