(Acetyl­acetonato-κ(2) O,O′)carbon­yl{dicyclo­hex­yl[4-(dimethyl­amino)­phen­yl]phosphane-κP}rhodium(I)

The title compound, [Rh(C(5)H(7)O(2))(C(20)H(32)NP)(CO)], features an acetyl­acetonate-chelated Rh(I) cation coordinated by one P [Rh—P = 2.2525 (7) Å], one carbonyl C [Rh—C = 1.792 (3) Å] and two O [Rh—O = 2.0582 (17) and 2.0912 (18) Å] atoms in a slightly distorted square-planar geometry. Mol­ecul...

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Detalles Bibliográficos
Autores principales: Davis, Wade L., Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238760/
https://www.ncbi.nlm.nih.gov/pubmed/22199637
http://dx.doi.org/10.1107/S1600536811050483
Descripción
Sumario:The title compound, [Rh(C(5)H(7)O(2))(C(20)H(32)NP)(CO)], features an acetyl­acetonate-chelated Rh(I) cation coordinated by one P [Rh—P = 2.2525 (7) Å], one carbonyl C [Rh—C = 1.792 (3) Å] and two O [Rh—O = 2.0582 (17) and 2.0912 (18) Å] atoms in a slightly distorted square-planar geometry. Mol­ecules are packed in positions of least steric hindrance, with the phosphane ligands positioned above and below the Rh–acetyl­acetonate backbone.

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