(Acetyl­acetonato-κ(2) O,O′)carbon­yl{dicyclo­hex­yl[4-(dimethyl­amino)­phen­yl]phosphane-κP}rhodium(I)

The title compound, [Rh(C(5)H(7)O(2))(C(20)H(32)NP)(CO)], features an acetyl­acetonate-chelated Rh(I) cation coordinated by one P [Rh—P = 2.2525 (7) Å], one carbonyl C [Rh—C = 1.792 (3) Å] and two O [Rh—O = 2.0582 (17) and 2.0912 (18) Å] atoms in a slightly distorted square-planar geometry. Mol­ecul...

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Detalles Bibliográficos
Autores principales: Davis, Wade L., Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238760/
https://www.ncbi.nlm.nih.gov/pubmed/22199637
http://dx.doi.org/10.1107/S1600536811050483
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author Davis, Wade L.
Meijboom, Reinout
author_facet Davis, Wade L.
Meijboom, Reinout
author_sort Davis, Wade L.
collection PubMed
description The title compound, [Rh(C(5)H(7)O(2))(C(20)H(32)NP)(CO)], features an acetyl­acetonate-chelated Rh(I) cation coordinated by one P [Rh—P = 2.2525 (7) Å], one carbonyl C [Rh—C = 1.792 (3) Å] and two O [Rh—O = 2.0582 (17) and 2.0912 (18) Å] atoms in a slightly distorted square-planar geometry. Mol­ecules are packed in positions of least steric hindrance, with the phosphane ligands positioned above and below the Rh–acetyl­acetonate backbone.
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spelling pubmed-32387602011-12-23 (Acetyl­acetonato-κ(2) O,O′)carbon­yl{dicyclo­hex­yl[4-(dimethyl­amino)­phen­yl]phosphane-κP}rhodium(I) Davis, Wade L. Meijboom, Reinout Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Rh(C(5)H(7)O(2))(C(20)H(32)NP)(CO)], features an acetyl­acetonate-chelated Rh(I) cation coordinated by one P [Rh—P = 2.2525 (7) Å], one carbonyl C [Rh—C = 1.792 (3) Å] and two O [Rh—O = 2.0582 (17) and 2.0912 (18) Å] atoms in a slightly distorted square-planar geometry. Mol­ecules are packed in positions of least steric hindrance, with the phosphane ligands positioned above and below the Rh–acetyl­acetonate backbone. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238760/ /pubmed/22199637 http://dx.doi.org/10.1107/S1600536811050483 Text en © Davis and Meijboom 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Davis, Wade L.
Meijboom, Reinout
(Acetyl­acetonato-κ(2) O,O′)carbon­yl{dicyclo­hex­yl[4-(dimethyl­amino)­phen­yl]phosphane-κP}rhodium(I)
title (Acetyl­acetonato-κ(2) O,O′)carbon­yl{dicyclo­hex­yl[4-(dimethyl­amino)­phen­yl]phosphane-κP}rhodium(I)
title_full (Acetyl­acetonato-κ(2) O,O′)carbon­yl{dicyclo­hex­yl[4-(dimethyl­amino)­phen­yl]phosphane-κP}rhodium(I)
title_fullStr (Acetyl­acetonato-κ(2) O,O′)carbon­yl{dicyclo­hex­yl[4-(dimethyl­amino)­phen­yl]phosphane-κP}rhodium(I)
title_full_unstemmed (Acetyl­acetonato-κ(2) O,O′)carbon­yl{dicyclo­hex­yl[4-(dimethyl­amino)­phen­yl]phosphane-κP}rhodium(I)
title_short (Acetyl­acetonato-κ(2) O,O′)carbon­yl{dicyclo­hex­yl[4-(dimethyl­amino)­phen­yl]phosphane-κP}rhodium(I)
title_sort (acetyl­acetonato-κ(2) o,o′)carbon­yl{dicyclo­hex­yl[4-(dimethyl­amino)­phen­yl]phosphane-κp}rhodium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238760/
https://www.ncbi.nlm.nih.gov/pubmed/22199637
http://dx.doi.org/10.1107/S1600536811050483
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AT meijboomreinout acetylacetonatok2oocarbonyldicyclohexyl4dimethylaminophenylphosphanekprhodiumi

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