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(2-Bromoacetyl)ferrocene
In the title molecule, [Fe(C(5)H(5))(C(7)H(6)BrO)], the C atoms of the substituted ring have disparate Fe—C bond lengths compared with the unsubstituted ring. In the bromoacetyl residue, the Br and O atoms are co-planar [the O—C—C—Br torsion angle is 5.7 (4)°] and are syn to each other. Helical su...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238761/ https://www.ncbi.nlm.nih.gov/pubmed/22199638 http://dx.doi.org/10.1107/S1600536811050434 |
Sumario: | In the title molecule, [Fe(C(5)H(5))(C(7)H(6)BrO)], the C atoms of the substituted ring have disparate Fe—C bond lengths compared with the unsubstituted ring. In the bromoacetyl residue, the Br and O atoms are co-planar [the O—C—C—Br torsion angle is 5.7 (4)°] and are syn to each other. Helical supramolecular chains along the b axis are formed in the crystal structure mediated by C—H⋯O contacts; the carbonyl-O atom is bifurcated. The chains are linked into layers by C—H⋯π(unsubstituted ring) interactions that stack along the a-axis direction. |
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