Cargando…

(2-Bromo­acet­yl)ferrocene

In the title mol­ecule, [Fe(C(5)H(5))(C(7)H(6)BrO)], the C atoms of the substituted ring have disparate Fe—C bond lengths compared with the unsubstituted ring. In the bromo­acetyl residue, the Br and O atoms are co-planar [the O—C—C—Br torsion angle is 5.7 (4)°] and are syn to each other. Helical su...

Descripción completa

Detalles Bibliográficos
Autores principales: Wu, Xiang-Xiang, Zhu, Xin, Ma, Qiu-Juan, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238761/
https://www.ncbi.nlm.nih.gov/pubmed/22199638
http://dx.doi.org/10.1107/S1600536811050434
Descripción
Sumario:In the title mol­ecule, [Fe(C(5)H(5))(C(7)H(6)BrO)], the C atoms of the substituted ring have disparate Fe—C bond lengths compared with the unsubstituted ring. In the bromo­acetyl residue, the Br and O atoms are co-planar [the O—C—C—Br torsion angle is 5.7 (4)°] and are syn to each other. Helical supra­molecular chains along the b axis are formed in the crystal structure mediated by C—H⋯O contacts; the carbonyl-O atom is bifurcated. The chains are linked into layers by C—H⋯π(unsubstituted ring) inter­actions that stack along the a-axis direction.