(2-Bromo­acet­yl)ferrocene

In the title mol­ecule, [Fe(C(5)H(5))(C(7)H(6)BrO)], the C atoms of the substituted ring have disparate Fe—C bond lengths compared with the unsubstituted ring. In the bromo­acetyl residue, the Br and O atoms are co-planar [the O—C—C—Br torsion angle is 5.7 (4)°] and are syn to each other. Helical su...

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Autores principales: Wu, Xiang-Xiang, Zhu, Xin, Ma, Qiu-Juan, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238761/
https://www.ncbi.nlm.nih.gov/pubmed/22199638
http://dx.doi.org/10.1107/S1600536811050434
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author Wu, Xiang-Xiang
Zhu, Xin
Ma, Qiu-Juan
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Wu, Xiang-Xiang
Zhu, Xin
Ma, Qiu-Juan
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Wu, Xiang-Xiang
collection PubMed
description In the title mol­ecule, [Fe(C(5)H(5))(C(7)H(6)BrO)], the C atoms of the substituted ring have disparate Fe—C bond lengths compared with the unsubstituted ring. In the bromo­acetyl residue, the Br and O atoms are co-planar [the O—C—C—Br torsion angle is 5.7 (4)°] and are syn to each other. Helical supra­molecular chains along the b axis are formed in the crystal structure mediated by C—H⋯O contacts; the carbonyl-O atom is bifurcated. The chains are linked into layers by C—H⋯π(unsubstituted ring) inter­actions that stack along the a-axis direction.
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spelling pubmed-32387612011-12-23 (2-Bromo­acet­yl)ferrocene Wu, Xiang-Xiang Zhu, Xin Ma, Qiu-Juan Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mol­ecule, [Fe(C(5)H(5))(C(7)H(6)BrO)], the C atoms of the substituted ring have disparate Fe—C bond lengths compared with the unsubstituted ring. In the bromo­acetyl residue, the Br and O atoms are co-planar [the O—C—C—Br torsion angle is 5.7 (4)°] and are syn to each other. Helical supra­molecular chains along the b axis are formed in the crystal structure mediated by C—H⋯O contacts; the carbonyl-O atom is bifurcated. The chains are linked into layers by C—H⋯π(unsubstituted ring) inter­actions that stack along the a-axis direction. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238761/ /pubmed/22199638 http://dx.doi.org/10.1107/S1600536811050434 Text en © Wu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Xiang-Xiang
Zhu, Xin
Ma, Qiu-Juan
Ng, Seik Weng
Tiekink, Edward R. T.
(2-Bromo­acet­yl)ferrocene
title (2-Bromo­acet­yl)ferrocene
title_full (2-Bromo­acet­yl)ferrocene
title_fullStr (2-Bromo­acet­yl)ferrocene
title_full_unstemmed (2-Bromo­acet­yl)ferrocene
title_short (2-Bromo­acet­yl)ferrocene
title_sort (2-bromo­acet­yl)ferrocene
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238761/
https://www.ncbi.nlm.nih.gov/pubmed/22199638
http://dx.doi.org/10.1107/S1600536811050434
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AT zhuxin 2bromoacetylferrocene
AT maqiujuan 2bromoacetylferrocene
AT ngseikweng 2bromoacetylferrocene
AT tiekinkedwardrt 2bromoacetylferrocene

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