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Bis[3-dimethyl­amino-1-(pyridin-2-yl)prop-2-en-1-one-κ(2) N (1),O]tris­(nitrato-κ(2) O,O)gadolinium(III) ethanol disolvate

In the title compound, [Gd(NO(3))(3)(C(10)H(12)N(2)O)(2)]·2C(2)H(5)OH, the Gd(III) ion and one nitrate anion are located on a twofold rotation axis. The Gd(III) ion is ten-coordinated by two N and two O atoms from two bidentate 3-(N,N-dimethyl­amino)-1-(2-pyrid­yl)prop-2-en-1-one) ligands and six O...

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Detalles Bibliográficos
Autores principales: Liu, Xia, Hu, Dahua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238762/
https://www.ncbi.nlm.nih.gov/pubmed/22199639
http://dx.doi.org/10.1107/S1600536811050458
Descripción
Sumario:In the title compound, [Gd(NO(3))(3)(C(10)H(12)N(2)O)(2)]·2C(2)H(5)OH, the Gd(III) ion and one nitrate anion are located on a twofold rotation axis. The Gd(III) ion is ten-coordinated by two N and two O atoms from two bidentate 3-(N,N-dimethyl­amino)-1-(2-pyrid­yl)prop-2-en-1-one) ligands and six O atoms from three nitrate anions in a distorted bicapped square-anti­prismatic geometry. In the crystal, the components are linked by O—H⋯O hydrogen bonds. The ethanol solvent mol­ecule is disordered over two positions in a ratio 0.615 (16):0.385 (16).