Bis[3-dimethyl­amino-1-(pyridin-2-yl)prop-2-en-1-one-κ(2) N (1),O]tris­(nitrato-κ(2) O,O)gadolinium(III) ethanol disolvate

In the title compound, [Gd(NO(3))(3)(C(10)H(12)N(2)O)(2)]·2C(2)H(5)OH, the Gd(III) ion and one nitrate anion are located on a twofold rotation axis. The Gd(III) ion is ten-coordinated by two N and two O atoms from two bidentate 3-(N,N-dimethyl­amino)-1-(2-pyrid­yl)prop-2-en-1-one) ligands and six O...

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Detalles Bibliográficos
Autores principales: Liu, Xia, Hu, Dahua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238762/
https://www.ncbi.nlm.nih.gov/pubmed/22199639
http://dx.doi.org/10.1107/S1600536811050458
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author Liu, Xia
Hu, Dahua
author_facet Liu, Xia
Hu, Dahua
author_sort Liu, Xia
collection PubMed
description In the title compound, [Gd(NO(3))(3)(C(10)H(12)N(2)O)(2)]·2C(2)H(5)OH, the Gd(III) ion and one nitrate anion are located on a twofold rotation axis. The Gd(III) ion is ten-coordinated by two N and two O atoms from two bidentate 3-(N,N-dimethyl­amino)-1-(2-pyrid­yl)prop-2-en-1-one) ligands and six O atoms from three nitrate anions in a distorted bicapped square-anti­prismatic geometry. In the crystal, the components are linked by O—H⋯O hydrogen bonds. The ethanol solvent mol­ecule is disordered over two positions in a ratio 0.615 (16):0.385 (16).
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spelling pubmed-32387622011-12-23 Bis[3-dimethyl­amino-1-(pyridin-2-yl)prop-2-en-1-one-κ(2) N (1),O]tris­(nitrato-κ(2) O,O)gadolinium(III) ethanol disolvate Liu, Xia Hu, Dahua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Gd(NO(3))(3)(C(10)H(12)N(2)O)(2)]·2C(2)H(5)OH, the Gd(III) ion and one nitrate anion are located on a twofold rotation axis. The Gd(III) ion is ten-coordinated by two N and two O atoms from two bidentate 3-(N,N-dimethyl­amino)-1-(2-pyrid­yl)prop-2-en-1-one) ligands and six O atoms from three nitrate anions in a distorted bicapped square-anti­prismatic geometry. In the crystal, the components are linked by O—H⋯O hydrogen bonds. The ethanol solvent mol­ecule is disordered over two positions in a ratio 0.615 (16):0.385 (16). International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238762/ /pubmed/22199639 http://dx.doi.org/10.1107/S1600536811050458 Text en © Liu and Hu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Xia
Hu, Dahua
Bis[3-dimethyl­amino-1-(pyridin-2-yl)prop-2-en-1-one-κ(2) N (1),O]tris­(nitrato-κ(2) O,O)gadolinium(III) ethanol disolvate
title Bis[3-dimethyl­amino-1-(pyridin-2-yl)prop-2-en-1-one-κ(2) N (1),O]tris­(nitrato-κ(2) O,O)gadolinium(III) ethanol disolvate
title_full Bis[3-dimethyl­amino-1-(pyridin-2-yl)prop-2-en-1-one-κ(2) N (1),O]tris­(nitrato-κ(2) O,O)gadolinium(III) ethanol disolvate
title_fullStr Bis[3-dimethyl­amino-1-(pyridin-2-yl)prop-2-en-1-one-κ(2) N (1),O]tris­(nitrato-κ(2) O,O)gadolinium(III) ethanol disolvate
title_full_unstemmed Bis[3-dimethyl­amino-1-(pyridin-2-yl)prop-2-en-1-one-κ(2) N (1),O]tris­(nitrato-κ(2) O,O)gadolinium(III) ethanol disolvate
title_short Bis[3-dimethyl­amino-1-(pyridin-2-yl)prop-2-en-1-one-κ(2) N (1),O]tris­(nitrato-κ(2) O,O)gadolinium(III) ethanol disolvate
title_sort bis[3-dimethyl­amino-1-(pyridin-2-yl)prop-2-en-1-one-κ(2) n (1),o]tris­(nitrato-κ(2) o,o)gadolinium(iii) ethanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238762/
https://www.ncbi.nlm.nih.gov/pubmed/22199639
http://dx.doi.org/10.1107/S1600536811050458
work_keys_str_mv AT liuxia bis3dimethylamino1pyridin2ylprop2en1onek2n1otrisnitratok2oogadoliniumiiiethanoldisolvate
AT hudahua bis3dimethylamino1pyridin2ylprop2en1onek2n1otrisnitratok2oogadoliniumiiiethanoldisolvate

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