catena-Poly[bis(dimethylazanium) [[chloridocopper(II)]-di-μ-chlorido-[chloridocopper(II)]-di-μ-azido-κ(4) N:N]]

The crystal structure of the title complex, {(C(2)H(8)N)[CuCl(2)(N(3))]}(n), exhibits inorganic chains consisting of Cu(II) cations as well azide and chloride anions. The chains, made up from Cu—Cl—Cu—N—Cu linkages, are aligned parallel to the c axis. This architecture is further stabilized by a num...

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Detalles Bibliográficos
Autores principales: Zhang, Wei-Yi, Yang, Li, Liu, Jie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238763/
https://www.ncbi.nlm.nih.gov/pubmed/22199640
http://dx.doi.org/10.1107/S1600536811050537
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author Zhang, Wei-Yi
Yang, Li
Liu, Jie
author_facet Zhang, Wei-Yi
Yang, Li
Liu, Jie
author_sort Zhang, Wei-Yi
collection PubMed
description The crystal structure of the title complex, {(C(2)H(8)N)[CuCl(2)(N(3))]}(n), exhibits inorganic chains consisting of Cu(II) cations as well azide and chloride anions. The chains, made up from Cu—Cl—Cu—N—Cu linkages, are aligned parallel to the c axis. This architecture is further stabilized by a number of N—H⋯Cl hydrogen bonds involving the protonated charge-compensating dimethyl­amine cations and chloride atoms.
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spelling pubmed-32387632011-12-23 catena-Poly[bis(dimethylazanium) [[chloridocopper(II)]-di-μ-chlorido-[chloridocopper(II)]-di-μ-azido-κ(4) N:N]] Zhang, Wei-Yi Yang, Li Liu, Jie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title complex, {(C(2)H(8)N)[CuCl(2)(N(3))]}(n), exhibits inorganic chains consisting of Cu(II) cations as well azide and chloride anions. The chains, made up from Cu—Cl—Cu—N—Cu linkages, are aligned parallel to the c axis. This architecture is further stabilized by a number of N—H⋯Cl hydrogen bonds involving the protonated charge-compensating dimethyl­amine cations and chloride atoms. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238763/ /pubmed/22199640 http://dx.doi.org/10.1107/S1600536811050537 Text en © Zhang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Wei-Yi
Yang, Li
Liu, Jie
catena-Poly[bis(dimethylazanium) [[chloridocopper(II)]-di-μ-chlorido-[chloridocopper(II)]-di-μ-azido-κ(4) N:N]]
title catena-Poly[bis(dimethylazanium) [[chloridocopper(II)]-di-μ-chlorido-[chloridocopper(II)]-di-μ-azido-κ(4) N:N]]
title_full catena-Poly[bis(dimethylazanium) [[chloridocopper(II)]-di-μ-chlorido-[chloridocopper(II)]-di-μ-azido-κ(4) N:N]]
title_fullStr catena-Poly[bis(dimethylazanium) [[chloridocopper(II)]-di-μ-chlorido-[chloridocopper(II)]-di-μ-azido-κ(4) N:N]]
title_full_unstemmed catena-Poly[bis(dimethylazanium) [[chloridocopper(II)]-di-μ-chlorido-[chloridocopper(II)]-di-μ-azido-κ(4) N:N]]
title_short catena-Poly[bis(dimethylazanium) [[chloridocopper(II)]-di-μ-chlorido-[chloridocopper(II)]-di-μ-azido-κ(4) N:N]]
title_sort catena-poly[bis(dimethylazanium) [[chloridocopper(ii)]-di-μ-chlorido-[chloridocopper(ii)]-di-μ-azido-κ(4) n:n]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238763/
https://www.ncbi.nlm.nih.gov/pubmed/22199640
http://dx.doi.org/10.1107/S1600536811050537
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AT liujie catenapolybisdimethylazaniumchloridocopperiidimchloridochloridocopperiidimazidok4nn

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