Tetra-n-butyl­ammonium tricyanido[N-(2-pyridyl­carbon­yl)pyridine-2-carbox­imidato]ferrate(III) dihydrate

In the title compound, (C(16)H(36)N)[Fe(C(12)H(8)N(3)O(2))(CN)(3)]·2H(2)O, the tetra-n-butyl­ammonium ion has a tetra­hedral configuration around the N atom, while the Fe(III) atom of the tricyanido[N-(2-pyridyl­carbon­yl)pyridine-2-carboximidato]iron(III) anion adopts a distorted octa­hedral geomet...

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Detalles Bibliográficos
Autores principales: Xiao, Yunyun, Shen, Xiaoping, Li, Yizhi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238764/
https://www.ncbi.nlm.nih.gov/pubmed/22199641
http://dx.doi.org/10.1107/S1600536811049415
Descripción
Sumario:In the title compound, (C(16)H(36)N)[Fe(C(12)H(8)N(3)O(2))(CN)(3)]·2H(2)O, the tetra-n-butyl­ammonium ion has a tetra­hedral configuration around the N atom, while the Fe(III) atom of the tricyanido[N-(2-pyridyl­carbon­yl)pyridine-2-carboximidato]iron(III) anion adopts a distorted octa­hedral geometry. O—H⋯O and O—H⋯N hydrogen bonds link the components in the crystal structure.

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