Tetra-n-butyl­ammonium tricyanido[N-(2-pyridyl­carbon­yl)pyridine-2-carbox­imidato]ferrate(III) dihydrate

In the title compound, (C(16)H(36)N)[Fe(C(12)H(8)N(3)O(2))(CN)(3)]·2H(2)O, the tetra-n-butyl­ammonium ion has a tetra­hedral configuration around the N atom, while the Fe(III) atom of the tricyanido[N-(2-pyridyl­carbon­yl)pyridine-2-carboximidato]iron(III) anion adopts a distorted octa­hedral geomet...

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Detalles Bibliográficos
Autores principales: Xiao, Yunyun, Shen, Xiaoping, Li, Yizhi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238764/
https://www.ncbi.nlm.nih.gov/pubmed/22199641
http://dx.doi.org/10.1107/S1600536811049415
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author Xiao, Yunyun
Shen, Xiaoping
Li, Yizhi
author_facet Xiao, Yunyun
Shen, Xiaoping
Li, Yizhi
author_sort Xiao, Yunyun
collection PubMed
description In the title compound, (C(16)H(36)N)[Fe(C(12)H(8)N(3)O(2))(CN)(3)]·2H(2)O, the tetra-n-butyl­ammonium ion has a tetra­hedral configuration around the N atom, while the Fe(III) atom of the tricyanido[N-(2-pyridyl­carbon­yl)pyridine-2-carboximidato]iron(III) anion adopts a distorted octa­hedral geometry. O—H⋯O and O—H⋯N hydrogen bonds link the components in the crystal structure.
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spelling pubmed-32387642011-12-23 Tetra-n-butyl­ammonium tricyanido[N-(2-pyridyl­carbon­yl)pyridine-2-carbox­imidato]ferrate(III) dihydrate Xiao, Yunyun Shen, Xiaoping Li, Yizhi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(16)H(36)N)[Fe(C(12)H(8)N(3)O(2))(CN)(3)]·2H(2)O, the tetra-n-butyl­ammonium ion has a tetra­hedral configuration around the N atom, while the Fe(III) atom of the tricyanido[N-(2-pyridyl­carbon­yl)pyridine-2-carboximidato]iron(III) anion adopts a distorted octa­hedral geometry. O—H⋯O and O—H⋯N hydrogen bonds link the components in the crystal structure. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238764/ /pubmed/22199641 http://dx.doi.org/10.1107/S1600536811049415 Text en © Xiao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xiao, Yunyun
Shen, Xiaoping
Li, Yizhi
Tetra-n-butyl­ammonium tricyanido[N-(2-pyridyl­carbon­yl)pyridine-2-carbox­imidato]ferrate(III) dihydrate
title Tetra-n-butyl­ammonium tricyanido[N-(2-pyridyl­carbon­yl)pyridine-2-carbox­imidato]ferrate(III) dihydrate
title_full Tetra-n-butyl­ammonium tricyanido[N-(2-pyridyl­carbon­yl)pyridine-2-carbox­imidato]ferrate(III) dihydrate
title_fullStr Tetra-n-butyl­ammonium tricyanido[N-(2-pyridyl­carbon­yl)pyridine-2-carbox­imidato]ferrate(III) dihydrate
title_full_unstemmed Tetra-n-butyl­ammonium tricyanido[N-(2-pyridyl­carbon­yl)pyridine-2-carbox­imidato]ferrate(III) dihydrate
title_short Tetra-n-butyl­ammonium tricyanido[N-(2-pyridyl­carbon­yl)pyridine-2-carbox­imidato]ferrate(III) dihydrate
title_sort tetra-n-butyl­ammonium tricyanido[n-(2-pyridyl­carbon­yl)pyridine-2-carbox­imidato]ferrate(iii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238764/
https://www.ncbi.nlm.nih.gov/pubmed/22199641
http://dx.doi.org/10.1107/S1600536811049415
work_keys_str_mv AT xiaoyunyun tetranbutylammoniumtricyanidon2pyridylcarbonylpyridine2carboximidatoferrateiiidihydrate
AT shenxiaoping tetranbutylammoniumtricyanidon2pyridylcarbonylpyridine2carboximidatoferrateiiidihydrate
AT liyizhi tetranbutylammoniumtricyanidon2pyridylcarbonylpyridine2carboximidatoferrateiiidihydrate

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