catena-Poly[[trimeth­yl(4-sulfanylphen­yl)aza­nium] [(chloridocadmate)-di-μ-chlorido]]

The title compound, {(C(9)H(14)NS)[CdCl(3)]}(n), consists of a linear [CdCl(3)](n)(n) (−) polyanion and a trimeth­yl(4-sulfanylphen­yl)aza­nium cation. The Cd(II) atom is penta­coordinated by four μ(2)-Cl atoms and one terminal Cl atom in a trigonal–bipyramidal geometry. The trigonal–bipyramidal uni...

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Detalles Bibliográficos
Autores principales: Tang, Xiao-Yan, Lang, Jian-Ping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238767/
https://www.ncbi.nlm.nih.gov/pubmed/22199644
http://dx.doi.org/10.1107/S1600536811050513
Descripción
Sumario:The title compound, {(C(9)H(14)NS)[CdCl(3)]}(n), consists of a linear [CdCl(3)](n)(n) (−) polyanion and a trimeth­yl(4-sulfanylphen­yl)aza­nium cation. The Cd(II) atom is penta­coordinated by four μ(2)-Cl atoms and one terminal Cl atom in a trigonal–bipyramidal geometry. The trigonal–bipyramidal units are linked by two opposite shared faces, giving rise to infinite [CdCl(3)](n) chains parallel to the a axis. The cations surround the chain and are linked to them by S—H⋯Cl and C—H⋯Cl hydrogen bonds, forming a three-dimensional network.

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