catena-Poly[[trimeth­yl(4-sulfanylphen­yl)aza­nium] [(chloridocadmate)-di-μ-chlorido]]

The title compound, {(C(9)H(14)NS)[CdCl(3)]}(n), consists of a linear [CdCl(3)](n)(n) (−) polyanion and a trimeth­yl(4-sulfanylphen­yl)aza­nium cation. The Cd(II) atom is penta­coordinated by four μ(2)-Cl atoms and one terminal Cl atom in a trigonal–bipyramidal geometry. The trigonal–bipyramidal uni...

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Detalles Bibliográficos
Autores principales: Tang, Xiao-Yan, Lang, Jian-Ping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238767/
https://www.ncbi.nlm.nih.gov/pubmed/22199644
http://dx.doi.org/10.1107/S1600536811050513
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author Tang, Xiao-Yan
Lang, Jian-Ping
author_facet Tang, Xiao-Yan
Lang, Jian-Ping
author_sort Tang, Xiao-Yan
collection PubMed
description The title compound, {(C(9)H(14)NS)[CdCl(3)]}(n), consists of a linear [CdCl(3)](n)(n) (−) polyanion and a trimeth­yl(4-sulfanylphen­yl)aza­nium cation. The Cd(II) atom is penta­coordinated by four μ(2)-Cl atoms and one terminal Cl atom in a trigonal–bipyramidal geometry. The trigonal–bipyramidal units are linked by two opposite shared faces, giving rise to infinite [CdCl(3)](n) chains parallel to the a axis. The cations surround the chain and are linked to them by S—H⋯Cl and C—H⋯Cl hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-32387672011-12-23 catena-Poly[[trimeth­yl(4-sulfanylphen­yl)aza­nium] [(chloridocadmate)-di-μ-chlorido]] Tang, Xiao-Yan Lang, Jian-Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {(C(9)H(14)NS)[CdCl(3)]}(n), consists of a linear [CdCl(3)](n)(n) (−) polyanion and a trimeth­yl(4-sulfanylphen­yl)aza­nium cation. The Cd(II) atom is penta­coordinated by four μ(2)-Cl atoms and one terminal Cl atom in a trigonal–bipyramidal geometry. The trigonal–bipyramidal units are linked by two opposite shared faces, giving rise to infinite [CdCl(3)](n) chains parallel to the a axis. The cations surround the chain and are linked to them by S—H⋯Cl and C—H⋯Cl hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238767/ /pubmed/22199644 http://dx.doi.org/10.1107/S1600536811050513 Text en © Tang and Lang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tang, Xiao-Yan
Lang, Jian-Ping
catena-Poly[[trimeth­yl(4-sulfanylphen­yl)aza­nium] [(chloridocadmate)-di-μ-chlorido]]
title catena-Poly[[trimeth­yl(4-sulfanylphen­yl)aza­nium] [(chloridocadmate)-di-μ-chlorido]]
title_full catena-Poly[[trimeth­yl(4-sulfanylphen­yl)aza­nium] [(chloridocadmate)-di-μ-chlorido]]
title_fullStr catena-Poly[[trimeth­yl(4-sulfanylphen­yl)aza­nium] [(chloridocadmate)-di-μ-chlorido]]
title_full_unstemmed catena-Poly[[trimeth­yl(4-sulfanylphen­yl)aza­nium] [(chloridocadmate)-di-μ-chlorido]]
title_short catena-Poly[[trimeth­yl(4-sulfanylphen­yl)aza­nium] [(chloridocadmate)-di-μ-chlorido]]
title_sort catena-poly[[trimeth­yl(4-sulfanylphen­yl)aza­nium] [(chloridocadmate)-di-μ-chlorido]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238767/
https://www.ncbi.nlm.nih.gov/pubmed/22199644
http://dx.doi.org/10.1107/S1600536811050513
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AT langjianping catenapolytrimethyl4sulfanylphenylazaniumchloridocadmatedimchlorido

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