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Di-μ-acetato-κ(4) O:O-bis­{(acetato-κ(2) O,O′)bis­[3-(1H-imidazol-1-yl-κN (3))-1-phenyl­propan-1-one]cadmium} tetra­hydrate

In the mol­ecular structure of the title neutral binuclear complex, [Cd(2)(C(2)H(3)O(2))(4)(C(12)H(12)N(2)O)(4)]·4H(2)O, each Cd(II) atom is six-coordinated and exhibits a distorted octa­hedral geometry. Three O atoms from two acetate ions and one monodentate 3-(1H-imidazol-1-yl-κN (3))-1-phenyl­pro...

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Autor principal: Guo, Jian-Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238768/
https://www.ncbi.nlm.nih.gov/pubmed/22199645
http://dx.doi.org/10.1107/S1600536811050021
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author Guo, Jian-Hua
author_facet Guo, Jian-Hua
author_sort Guo, Jian-Hua
collection PubMed
description In the mol­ecular structure of the title neutral binuclear complex, [Cd(2)(C(2)H(3)O(2))(4)(C(12)H(12)N(2)O)(4)]·4H(2)O, each Cd(II) atom is six-coordinated and exhibits a distorted octa­hedral geometry. Three O atoms from two acetate ions and one monodentate 3-(1H-imidazol-1-yl-κN (3))-1-phenyl­propan-1-one (L) ligand form the equatorial plane, while the bridging-O atom forming the longer Cd—O distance,and the N atom of the second L ligand, forming the longer Cd—N distance, occupy axial positions with an N—Cd—O angle of 170.77 (7)°. Inter­molecular O—H⋯O hydrogen bonds exist between the lattice water mol­ecules and the acetate ions of adjacent mol­ecules, resulting in a two-dimensional supra­molecular structure.
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spelling pubmed-32387682011-12-23 Di-μ-acetato-κ(4) O:O-bis­{(acetato-κ(2) O,O′)bis­[3-(1H-imidazol-1-yl-κN (3))-1-phenyl­propan-1-one]cadmium} tetra­hydrate Guo, Jian-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mol­ecular structure of the title neutral binuclear complex, [Cd(2)(C(2)H(3)O(2))(4)(C(12)H(12)N(2)O)(4)]·4H(2)O, each Cd(II) atom is six-coordinated and exhibits a distorted octa­hedral geometry. Three O atoms from two acetate ions and one monodentate 3-(1H-imidazol-1-yl-κN (3))-1-phenyl­propan-1-one (L) ligand form the equatorial plane, while the bridging-O atom forming the longer Cd—O distance,and the N atom of the second L ligand, forming the longer Cd—N distance, occupy axial positions with an N—Cd—O angle of 170.77 (7)°. Inter­molecular O—H⋯O hydrogen bonds exist between the lattice water mol­ecules and the acetate ions of adjacent mol­ecules, resulting in a two-dimensional supra­molecular structure. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238768/ /pubmed/22199645 http://dx.doi.org/10.1107/S1600536811050021 Text en © Jian-Hua Guo 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Jian-Hua
Di-μ-acetato-κ(4) O:O-bis­{(acetato-κ(2) O,O′)bis­[3-(1H-imidazol-1-yl-κN (3))-1-phenyl­propan-1-one]cadmium} tetra­hydrate
title Di-μ-acetato-κ(4) O:O-bis­{(acetato-κ(2) O,O′)bis­[3-(1H-imidazol-1-yl-κN (3))-1-phenyl­propan-1-one]cadmium} tetra­hydrate
title_full Di-μ-acetato-κ(4) O:O-bis­{(acetato-κ(2) O,O′)bis­[3-(1H-imidazol-1-yl-κN (3))-1-phenyl­propan-1-one]cadmium} tetra­hydrate
title_fullStr Di-μ-acetato-κ(4) O:O-bis­{(acetato-κ(2) O,O′)bis­[3-(1H-imidazol-1-yl-κN (3))-1-phenyl­propan-1-one]cadmium} tetra­hydrate
title_full_unstemmed Di-μ-acetato-κ(4) O:O-bis­{(acetato-κ(2) O,O′)bis­[3-(1H-imidazol-1-yl-κN (3))-1-phenyl­propan-1-one]cadmium} tetra­hydrate
title_short Di-μ-acetato-κ(4) O:O-bis­{(acetato-κ(2) O,O′)bis­[3-(1H-imidazol-1-yl-κN (3))-1-phenyl­propan-1-one]cadmium} tetra­hydrate
title_sort di-μ-acetato-κ(4) o:o-bis­{(acetato-κ(2) o,o′)bis­[3-(1h-imidazol-1-yl-κn (3))-1-phenyl­propan-1-one]cadmium} tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238768/
https://www.ncbi.nlm.nih.gov/pubmed/22199645
http://dx.doi.org/10.1107/S1600536811050021
work_keys_str_mv AT guojianhua dimacetatok4oobisacetatok2oobis31himidazol1ylkn31phenylpropan1onecadmiumtetrahydrate