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Di-μ-acetato-κ(4) O:O-bis{(acetato-κ(2) O,O′)bis[3-(1H-imidazol-1-yl-κN (3))-1-phenylpropan-1-one]cadmium} tetrahydrate
In the molecular structure of the title neutral binuclear complex, [Cd(2)(C(2)H(3)O(2))(4)(C(12)H(12)N(2)O)(4)]·4H(2)O, each Cd(II) atom is six-coordinated and exhibits a distorted octahedral geometry. Three O atoms from two acetate ions and one monodentate 3-(1H-imidazol-1-yl-κN (3))-1-phenylpro...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238768/ https://www.ncbi.nlm.nih.gov/pubmed/22199645 http://dx.doi.org/10.1107/S1600536811050021 |
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author | Guo, Jian-Hua |
author_facet | Guo, Jian-Hua |
author_sort | Guo, Jian-Hua |
collection | PubMed |
description | In the molecular structure of the title neutral binuclear complex, [Cd(2)(C(2)H(3)O(2))(4)(C(12)H(12)N(2)O)(4)]·4H(2)O, each Cd(II) atom is six-coordinated and exhibits a distorted octahedral geometry. Three O atoms from two acetate ions and one monodentate 3-(1H-imidazol-1-yl-κN (3))-1-phenylpropan-1-one (L) ligand form the equatorial plane, while the bridging-O atom forming the longer Cd—O distance,and the N atom of the second L ligand, forming the longer Cd—N distance, occupy axial positions with an N—Cd—O angle of 170.77 (7)°. Intermolecular O—H⋯O hydrogen bonds exist between the lattice water molecules and the acetate ions of adjacent molecules, resulting in a two-dimensional supramolecular structure. |
format | Online Article Text |
id | pubmed-3238768 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32387682011-12-23 Di-μ-acetato-κ(4) O:O-bis{(acetato-κ(2) O,O′)bis[3-(1H-imidazol-1-yl-κN (3))-1-phenylpropan-1-one]cadmium} tetrahydrate Guo, Jian-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the molecular structure of the title neutral binuclear complex, [Cd(2)(C(2)H(3)O(2))(4)(C(12)H(12)N(2)O)(4)]·4H(2)O, each Cd(II) atom is six-coordinated and exhibits a distorted octahedral geometry. Three O atoms from two acetate ions and one monodentate 3-(1H-imidazol-1-yl-κN (3))-1-phenylpropan-1-one (L) ligand form the equatorial plane, while the bridging-O atom forming the longer Cd—O distance,and the N atom of the second L ligand, forming the longer Cd—N distance, occupy axial positions with an N—Cd—O angle of 170.77 (7)°. Intermolecular O—H⋯O hydrogen bonds exist between the lattice water molecules and the acetate ions of adjacent molecules, resulting in a two-dimensional supramolecular structure. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238768/ /pubmed/22199645 http://dx.doi.org/10.1107/S1600536811050021 Text en © Jian-Hua Guo 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Guo, Jian-Hua Di-μ-acetato-κ(4) O:O-bis{(acetato-κ(2) O,O′)bis[3-(1H-imidazol-1-yl-κN (3))-1-phenylpropan-1-one]cadmium} tetrahydrate |
title | Di-μ-acetato-κ(4)
O:O-bis{(acetato-κ(2)
O,O′)bis[3-(1H-imidazol-1-yl-κN
(3))-1-phenylpropan-1-one]cadmium} tetrahydrate |
title_full | Di-μ-acetato-κ(4)
O:O-bis{(acetato-κ(2)
O,O′)bis[3-(1H-imidazol-1-yl-κN
(3))-1-phenylpropan-1-one]cadmium} tetrahydrate |
title_fullStr | Di-μ-acetato-κ(4)
O:O-bis{(acetato-κ(2)
O,O′)bis[3-(1H-imidazol-1-yl-κN
(3))-1-phenylpropan-1-one]cadmium} tetrahydrate |
title_full_unstemmed | Di-μ-acetato-κ(4)
O:O-bis{(acetato-κ(2)
O,O′)bis[3-(1H-imidazol-1-yl-κN
(3))-1-phenylpropan-1-one]cadmium} tetrahydrate |
title_short | Di-μ-acetato-κ(4)
O:O-bis{(acetato-κ(2)
O,O′)bis[3-(1H-imidazol-1-yl-κN
(3))-1-phenylpropan-1-one]cadmium} tetrahydrate |
title_sort | di-μ-acetato-κ(4)
o:o-bis{(acetato-κ(2)
o,o′)bis[3-(1h-imidazol-1-yl-κn
(3))-1-phenylpropan-1-one]cadmium} tetrahydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238768/ https://www.ncbi.nlm.nih.gov/pubmed/22199645 http://dx.doi.org/10.1107/S1600536811050021 |
work_keys_str_mv | AT guojianhua dimacetatok4oobisacetatok2oobis31himidazol1ylkn31phenylpropan1onecadmiumtetrahydrate |