Bis(2,4-dioxo-5,5-diphenyl­imidazol­idin­ido-κN (3))bis­(propane-1,3-diamine-κ(2) N,N′)cobalt(II)

The complex mol­ecule of the title compound, [Co(C(15)H(11)N(2)O(2))(2)(C(3)H(10)N(2))(2)], has crystallographically imposed inversion symmetry. The Co(II) atom displays a distorted octa­hedral coordination geometry. In the phenytoin anion, the two phenyl rings form dihedral angles of 62.26 (8) and...

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Detalles Bibliográficos
Autores principales: Hu, Xilan, Jiang, Qing, Wang, Daqi, Liu, Haifeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238769/
https://www.ncbi.nlm.nih.gov/pubmed/22199646
http://dx.doi.org/10.1107/S1600536811050252
Descripción
Sumario:The complex mol­ecule of the title compound, [Co(C(15)H(11)N(2)O(2))(2)(C(3)H(10)N(2))(2)], has crystallographically imposed inversion symmetry. The Co(II) atom displays a distorted octa­hedral coordination geometry. In the phenytoin anion, the two phenyl rings form dihedral angles of 62.26 (8) and 57.47 (9)° with the central imidazole ring. Intra­molecular N—H⋯O and C—H⋯O hydrogen bonds occur. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds forming a three-dimensional network.

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