Bis(2,4-dioxo-5,5-diphenyl­imidazol­idin­ido-κN (3))bis­(propane-1,3-diamine-κ(2) N,N′)cobalt(II)

The complex mol­ecule of the title compound, [Co(C(15)H(11)N(2)O(2))(2)(C(3)H(10)N(2))(2)], has crystallographically imposed inversion symmetry. The Co(II) atom displays a distorted octa­hedral coordination geometry. In the phenytoin anion, the two phenyl rings form dihedral angles of 62.26 (8) and...

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Detalles Bibliográficos
Autores principales: Hu, Xilan, Jiang, Qing, Wang, Daqi, Liu, Haifeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238769/
https://www.ncbi.nlm.nih.gov/pubmed/22199646
http://dx.doi.org/10.1107/S1600536811050252
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author Hu, Xilan
Jiang, Qing
Wang, Daqi
Liu, Haifeng
author_facet Hu, Xilan
Jiang, Qing
Wang, Daqi
Liu, Haifeng
author_sort Hu, Xilan
collection PubMed
description The complex mol­ecule of the title compound, [Co(C(15)H(11)N(2)O(2))(2)(C(3)H(10)N(2))(2)], has crystallographically imposed inversion symmetry. The Co(II) atom displays a distorted octa­hedral coordination geometry. In the phenytoin anion, the two phenyl rings form dihedral angles of 62.26 (8) and 57.47 (9)° with the central imidazole ring. Intra­molecular N—H⋯O and C—H⋯O hydrogen bonds occur. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds forming a three-dimensional network.
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spelling pubmed-32387692011-12-23 Bis(2,4-dioxo-5,5-diphenyl­imidazol­idin­ido-κN (3))bis­(propane-1,3-diamine-κ(2) N,N′)cobalt(II) Hu, Xilan Jiang, Qing Wang, Daqi Liu, Haifeng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complex mol­ecule of the title compound, [Co(C(15)H(11)N(2)O(2))(2)(C(3)H(10)N(2))(2)], has crystallographically imposed inversion symmetry. The Co(II) atom displays a distorted octa­hedral coordination geometry. In the phenytoin anion, the two phenyl rings form dihedral angles of 62.26 (8) and 57.47 (9)° with the central imidazole ring. Intra­molecular N—H⋯O and C—H⋯O hydrogen bonds occur. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds forming a three-dimensional network. International Union of Crystallography 2011-11-30 /pmc/articles/PMC3238769/ /pubmed/22199646 http://dx.doi.org/10.1107/S1600536811050252 Text en © Hu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hu, Xilan
Jiang, Qing
Wang, Daqi
Liu, Haifeng
Bis(2,4-dioxo-5,5-diphenyl­imidazol­idin­ido-κN (3))bis­(propane-1,3-diamine-κ(2) N,N′)cobalt(II)
title Bis(2,4-dioxo-5,5-diphenyl­imidazol­idin­ido-κN (3))bis­(propane-1,3-diamine-κ(2) N,N′)cobalt(II)
title_full Bis(2,4-dioxo-5,5-diphenyl­imidazol­idin­ido-κN (3))bis­(propane-1,3-diamine-κ(2) N,N′)cobalt(II)
title_fullStr Bis(2,4-dioxo-5,5-diphenyl­imidazol­idin­ido-κN (3))bis­(propane-1,3-diamine-κ(2) N,N′)cobalt(II)
title_full_unstemmed Bis(2,4-dioxo-5,5-diphenyl­imidazol­idin­ido-κN (3))bis­(propane-1,3-diamine-κ(2) N,N′)cobalt(II)
title_short Bis(2,4-dioxo-5,5-diphenyl­imidazol­idin­ido-κN (3))bis­(propane-1,3-diamine-κ(2) N,N′)cobalt(II)
title_sort bis(2,4-dioxo-5,5-diphenyl­imidazol­idin­ido-κn (3))bis­(propane-1,3-diamine-κ(2) n,n′)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238769/
https://www.ncbi.nlm.nih.gov/pubmed/22199646
http://dx.doi.org/10.1107/S1600536811050252
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AT liuhaifeng bis24dioxo55diphenylimidazolidinidokn3bispropane13diaminek2nncobaltii

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