Bis{μ-4-chloro-N′-[(E)-1-(5-chloro-2-oxidophen­yl)ethyl­idene]benzohydrazidato}bis­[pyridine­copper(II)]

The crystal structure of the title complex, [Cu(2)(C(15)H(10)Cl(2)N(2)O(2))(2)(C(5)H(5)N)(2)], features centrosymmetric dimers. The Cu(II) ion is penta­coordinated in a quadratic pyramidal mode. The quadratic plane is formed by the O,O′,N-tridentate ligand and a pyridine mol­ecule. The fifth coordin...

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Detalles Bibliográficos
Autor principal: Chang, Jian-Guo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238770/
https://www.ncbi.nlm.nih.gov/pubmed/22199647
http://dx.doi.org/10.1107/S1600536811050720
Descripción
Sumario:The crystal structure of the title complex, [Cu(2)(C(15)H(10)Cl(2)N(2)O(2))(2)(C(5)H(5)N)(2)], features centrosymmetric dimers. The Cu(II) ion is penta­coordinated in a quadratic pyramidal mode. The quadratic plane is formed by the O,O′,N-tridentate ligand and a pyridine mol­ecule. The fifth coordination site is occupied by the O atom of another ligand showing a significantly longer Cu—O bond.

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